TY - JOUR
T1 - Heterolysis of Re2O7
T2 - Generation and Stabilization of the Cation [ReO3]+
AU - Herrmann, Wolfgang A.
AU - Roesky, Peter W.
AU - Kühn, Fritz E.
AU - Scherer, Wolfgang
AU - Kleine, Matthias
PY - 1993/12
Y1 - 1993/12
N2 - No side products and no change in the oxidation state of the metal are observed in the cleavage of Re2O7 into [ReO3]+ and [ReO4]−, if the cation is generated and stabilized by open‐chain or cyclic tridentate donor ligands (XNH, NCH3, S in 1). The heterolysis, which is driven by coordination chemistry factors, is set up by an unsymmetric solvation of Re2O7 in donor solvents like THE. (Figure Presented.)
AB - No side products and no change in the oxidation state of the metal are observed in the cleavage of Re2O7 into [ReO3]+ and [ReO4]−, if the cation is generated and stabilized by open‐chain or cyclic tridentate donor ligands (XNH, NCH3, S in 1). The heterolysis, which is driven by coordination chemistry factors, is set up by an unsymmetric solvation of Re2O7 in donor solvents like THE. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748234284&partnerID=8YFLogxK
U2 - 10.1002/anie.199317141
DO - 10.1002/anie.199317141
M3 - Article
AN - SCOPUS:33748234284
SN - 0570-0833
VL - 32
SP - 1714
EP - 1716
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -