Heterogeneous catalytic oxidation by MFU-1: A Cobalt(II)-Containing metal-organic framework

Markus Tonigold, Ying Tu, Björn Bredenkötter, Bernhard Rieger, Stefan Bahnmüller, Julia Hitzbleck, Gerhard Langstein, Dirk Volkmer

Research output: Contribution to journalArticlepeer-review

185 Scopus citations

Abstract

Structurally related to MOF-5, the cobalt(II)-containing metal-organic framework MFU-1 is stable to hydrolysis. Catalytic turnover is achieved in oxidation reactions with redox-active MFU- 1, and the solid catalyst is easily recovered from the reaction mixture. Catalytic transformations have been shown to occur inside the pores of the microporous solid.

Original languageEnglish
Pages (from-to)7546-7550
Number of pages5
JournalAngewandte Chemie International Edition in English
Volume48
Issue number41
DOIs
StatePublished - 28 Sep 2009

Keywords

  • Metal-organic frameworks
  • Microwave synthesis
  • Oxidation catalysis
  • Porous solids
  • Redox-active frameworks

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