Heteroatomic Si/Ge zintl clusters: Single-crystal structure determination of Rb4[Si7.8Ge1.2](NH3)5 and [Rb([18]crown-6)Rb3][Si7.5Ge1.5](NH 3)4

Markus Waibel; Christian B. Benda; Bernhard Wahl; Thomas F. Fässler

doi:10.1002/chem.201101393

Heteroatomic Si/Ge zintl clusters: Single-crystal structure determination of Rb₄[Si_7.8Ge_1.2](NH₃)₅ and [Rb([18]crown-6)Rb₃][Si_7.5Ge_1.5](NH ₃)₄

Markus Waibel
, Christian B. Benda
, Bernhard Wahl
, Thomas F. Fässler

Chair of Inorganic Chemistry with Focus on New Materials

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Towards silicon microelectronics: Dissolution of the heteroatomic Group 14 element Zintl phase Rb₁₂Si₁₂Ge₅ in liquid ammonia led to the isolation of two [E₉]^4- clusters with Si and Ge mixed site occupation. The existence of [Si_7.5(1)Ge _1.5(1)]^4- and [Si_7.8(1)Ge_1.2(1)] ^4- as soluble ions opens new synthetic routes for mixed metal semiconductors (see figure).

Original language	English
Pages (from-to)	12928-12931
Number of pages	4
Journal	Chemistry - A European Journal
Volume	17
Issue number	46
DOIs	https://doi.org/10.1002/chem.201101393
State	Published - 11 Nov 2011

Keywords

cluster compounds
germanium
silicon
zintl anions
zintl phases

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title = "Heteroatomic Si/Ge zintl clusters: Single-crystal structure determination of Rb4[Si7.8Ge1.2](NH3)5 and [Rb([18]crown-6)Rb3][Si7.5Ge1.5](NH 3)4",

abstract = "Towards silicon microelectronics: Dissolution of the heteroatomic Group 14 element Zintl phase Rb12Si12Ge5 in liquid ammonia led to the isolation of two [E9]4- clusters with Si and Ge mixed site occupation. The existence of [Si7.5(1)Ge 1.5(1)]4- and [Si7.8(1)Ge1.2(1)] 4- as soluble ions opens new synthetic routes for mixed metal semiconductors (see figure).",

keywords = "cluster compounds, germanium, silicon, zintl anions, zintl phases",

author = "Markus Waibel and Benda, \{Christian B.\} and Bernhard Wahl and F{\"a}ssler, \{Thomas F.\}",

year = "2011",

month = nov,

day = "11",

doi = "10.1002/chem.201101393",

language = "English",

volume = "17",

pages = "12928--12931",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc.",

number = "46",

}

TY - JOUR

T1 - Heteroatomic Si/Ge zintl clusters

T2 - Single-crystal structure determination of Rb4[Si7.8Ge1.2](NH3)5 and [Rb([18]crown-6)Rb3][Si7.5Ge1.5](NH 3)4

AU - Waibel, Markus

AU - Benda, Christian B.

AU - Wahl, Bernhard

AU - Fässler, Thomas F.

PY - 2011/11/11

Y1 - 2011/11/11

N2 - Towards silicon microelectronics: Dissolution of the heteroatomic Group 14 element Zintl phase Rb12Si12Ge5 in liquid ammonia led to the isolation of two [E9]4- clusters with Si and Ge mixed site occupation. The existence of [Si7.5(1)Ge 1.5(1)]4- and [Si7.8(1)Ge1.2(1)] 4- as soluble ions opens new synthetic routes for mixed metal semiconductors (see figure).

AB - Towards silicon microelectronics: Dissolution of the heteroatomic Group 14 element Zintl phase Rb12Si12Ge5 in liquid ammonia led to the isolation of two [E9]4- clusters with Si and Ge mixed site occupation. The existence of [Si7.5(1)Ge 1.5(1)]4- and [Si7.8(1)Ge1.2(1)] 4- as soluble ions opens new synthetic routes for mixed metal semiconductors (see figure).

KW - cluster compounds

KW - germanium

KW - silicon

KW - zintl anions

KW - zintl phases

UR - https://www.scopus.com/pages/publications/80555127331

U2 - 10.1002/chem.201101393

DO - 10.1002/chem.201101393

M3 - Article

AN - SCOPUS:80555127331

SN - 0947-6539

VL - 17

SP - 12928

EP - 12931

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 46

ER -

Heteroatomic Si/Ge zintl clusters: Single-crystal structure determination of Rb₄[Si_7.8Ge_1.2](NH₃)₅ and [Rb([18]crown-6)Rb₃][Si_7.5Ge_1.5](NH ₃)₄

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