Heavy-atom effect in the electron-phonon coupling of naphthalene X-traps

G. Weinzierl; J. Friedrich

doi:10.1016/0009-2614(81)85616-3

Heavy-atom effect in the electron-phonon coupling of naphthalene X-traps

G. Weinzierl, J. Friedrich

Department of Physics

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

We investigated electron-phonon coupling in phosphorescence from X-traps of a naphthalene crystal at 1.2 K. X-traps were created by doping the crystal with β-halonaphthalenes. The results show that the electron-phonon coupling increases with increasing mass of the heavy atom. In the iodine X-trap, multiphonon structure is detectable. The results are interpreted as a charge-transfer interaction with the adjacent heavy atom.

Original language	English
Pages (from-to)	139-142
Number of pages	4
Journal	Chemical Physics Letters
Volume	77
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(81)85616-3
State	Published - 1 Jan 1981

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title = "Heavy-atom effect in the electron-phonon coupling of naphthalene X-traps",

abstract = "We investigated electron-phonon coupling in phosphorescence from X-traps of a naphthalene crystal at 1.2 K. X-traps were created by doping the crystal with β-halonaphthalenes. The results show that the electron-phonon coupling increases with increasing mass of the heavy atom. In the iodine X-trap, multiphonon structure is detectable. The results are interpreted as a charge-transfer interaction with the adjacent heavy atom.",

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N2 - We investigated electron-phonon coupling in phosphorescence from X-traps of a naphthalene crystal at 1.2 K. X-traps were created by doping the crystal with β-halonaphthalenes. The results show that the electron-phonon coupling increases with increasing mass of the heavy atom. In the iodine X-trap, multiphonon structure is detectable. The results are interpreted as a charge-transfer interaction with the adjacent heavy atom.

AB - We investigated electron-phonon coupling in phosphorescence from X-traps of a naphthalene crystal at 1.2 K. X-traps were created by doping the crystal with β-halonaphthalenes. The results show that the electron-phonon coupling increases with increasing mass of the heavy atom. In the iodine X-trap, multiphonon structure is detectable. The results are interpreted as a charge-transfer interaction with the adjacent heavy atom.

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Heavy-atom effect in the electron-phonon coupling of naphthalene X-traps

Abstract

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