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Growth mechanism of metal-organic frameworks: Insights into the nucleation by employing a step-by-step route

  • Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journalArticlepeer-review

379 Scopus citations

Abstract

One step at a time: The in situ monitoring of the step-bystep formation of metal-organic frameworks (MOFs) by using surface plasmon resonance (SPR), allows the nucleation process and the formation of the secondary building units to be investigated. Growth rates on functionalized organic surfaces with different crystallographic orientations can also be studied.

Original languageEnglish
Pages (from-to)5038-5041
Number of pages4
JournalAngewandte Chemie International Edition in English
Volume48
Issue number27
DOIs
StatePublished - 22 Jun 2009
Externally publishedYes

Keywords

  • Mechanistic studies
  • Metal-organic frameworks
  • Monolayers
  • Nucleation
  • Secondary building blocks

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