Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

Ayyamperumal Sakthivel; Filipe M. Pedro; Anthony S.T. Chiang; Fritz E. Kühn

doi:10.1039/b611550k

Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

Ayyamperumal Sakthivel, Filipe M. Pedro, Anthony S.T. Chiang, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N₂ adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

Original language	English
Pages (from-to)	320-326
Number of pages	7
Journal	Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/b611550k
State	Published - 2007

Access to Document

10.1039/b611550k

Cite this

@article{e612d750313d4e1699c75c3cce562448,

title = "Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates",

abstract = "Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.",

author = "Ayyamperumal Sakthivel and Pedro, {Filipe M.} and Chiang, {Anthony S.T.} and K{\"u}hn, {Fritz E.}",

year = "2007",

doi = "10.1039/b611550k",

language = "English",

pages = "320--326",

journal = "Dalton Transactions",

issn = "1477-9226",

number = "3",

}

TY - JOUR

T1 - Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

AU - Sakthivel, Ayyamperumal

AU - Pedro, Filipe M.

AU - Chiang, Anthony S.T.

AU - Kühn, Fritz E.

PY - 2007

Y1 - 2007

N2 - Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

AB - Cyclopentadienyl ruthenium phosphane and carbene complexes are grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, DRIFTS, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted materials are applied for catalytic aldehyde olefination and cyclopropanation.

UR - http://www.scopus.com/inward/record.url?scp=33845986745&partnerID=8YFLogxK

U2 - 10.1039/b611550k

DO - 10.1039/b611550k

M3 - Article

AN - SCOPUS:33845986745

SN - 1477-9226

SP - 320

EP - 326

JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

Grafting of cyclopentadienyl ruthenium complexes on aminosilane linker modified mesoporous SBA-15 silicates

Abstract

Access to Document

Other files and links

Fingerprint

Cite this