Grafting of [Cu(NCCH3)6][B{C6H3(m-CF3)2}4]2 on the surface of aminosilane modified SBA-15

Ayyamperumal Sakthivel; Ahmed K. Hijazi; Akef I. Al Hmaideen; Fritz E. Kühn

doi:10.1016/j.micromeso.2006.07.009

Grafting of [Cu(NCCH₃)₆][B{C₆H₃(m-CF₃)₂}₄]₂ on the surface of aminosilane modified SBA-15

Ayyamperumal Sakthivel
, Ahmed K. Hijazi
, Akef I. Al Hmaideen
, Fritz E. Kühn

Instituto Tecnológico E Nuclear

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A copper complex with weakly coordinating anions is grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N₂ adsorption/desorption analysis. Elemental analysis, FT-IR, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted material is applied as catalysts for aldehyde olefination.

Original language	English
Pages (from-to)	293-300
Number of pages	8
Journal	Microporous and Mesoporous Materials
Volume	96
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2006.07.009
State	Published - 26 Nov 2006
Externally published	Yes

Keywords

Aldehyde olefination
Copper acetonitrile complex
Grafting
Mesoporous materials
SBA-15

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10.1016/j.micromeso.2006.07.009

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title = "Grafting of [Cu(NCCH3)6][B\{C6H3(m-CF3)2\}4]2 on the surface of aminosilane modified SBA-15",

abstract = "A copper complex with weakly coordinating anions is grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted material is applied as catalysts for aldehyde olefination.",

keywords = "Aldehyde olefination, Copper acetonitrile complex, Grafting, Mesoporous materials, SBA-15",

author = "Ayyamperumal Sakthivel and Hijazi, \{Ahmed K.\} and \{Al Hmaideen\}, \{Akef I.\} and K{\"u}hn, \{Fritz E.\}",

year = "2006",

month = nov,

day = "26",

doi = "10.1016/j.micromeso.2006.07.009",

language = "English",

volume = "96",

pages = "293--300",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Grafting of [Cu(NCCH3)6][B{C6H3(m-CF3)2}4]2 on the surface of aminosilane modified SBA-15

AU - Sakthivel, Ayyamperumal

AU - Hijazi, Ahmed K.

AU - Al Hmaideen, Akef I.

AU - Kühn, Fritz E.

PY - 2006/11/26

Y1 - 2006/11/26

N2 - A copper complex with weakly coordinating anions is grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted material is applied as catalysts for aldehyde olefination.

AB - A copper complex with weakly coordinating anions is grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted material is applied as catalysts for aldehyde olefination.

KW - Aldehyde olefination

KW - Copper acetonitrile complex

KW - Grafting

KW - Mesoporous materials

KW - SBA-15

UR - https://www.scopus.com/pages/publications/33750358248

U2 - 10.1016/j.micromeso.2006.07.009

DO - 10.1016/j.micromeso.2006.07.009

M3 - Article

AN - SCOPUS:33750358248

SN - 1387-1811

VL - 96

SP - 293

EP - 300

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

Grafting of [Cu(NCCH₃)₆][B{C₆H₃(m-CF₃)₂}₄]₂ on the surface of aminosilane modified SBA-15

Abstract

Keywords

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