TY - JOUR
T1 - Grafting of [Cu(NCCH3)6][B{C6H3(m-CF3)2}4]2 on the surface of aminosilane modified SBA-15
AU - Sakthivel, Ayyamperumal
AU - Hijazi, Ahmed K.
AU - Al Hmaideen, Akef I.
AU - Kühn, Fritz E.
PY - 2006/11/26
Y1 - 2006/11/26
N2 - A copper complex with weakly coordinating anions is grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted material is applied as catalysts for aldehyde olefination.
AB - A copper complex with weakly coordinating anions is grafted on the surface of mesoporous SBA-15 molecular sieves through an aminosilane linker. The nature of the support after the grafting is examined by powder XRD, TEM and N2 adsorption/desorption analysis. Elemental analysis, FT-IR, TG-MS and MAS-NMR studies confirm the successful grafting of the complexes on the surface. The grafted material is applied as catalysts for aldehyde olefination.
KW - Aldehyde olefination
KW - Copper acetonitrile complex
KW - Grafting
KW - Mesoporous materials
KW - SBA-15
UR - http://www.scopus.com/inward/record.url?scp=33750358248&partnerID=8YFLogxK
U2 - 10.1016/j.micromeso.2006.07.009
DO - 10.1016/j.micromeso.2006.07.009
M3 - Article
AN - SCOPUS:33750358248
SN - 1387-1811
VL - 96
SP - 293
EP - 300
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
IS - 1-3
ER -