Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials

Ayyamperumal Sakthivel; Marta Abrantes; Anthony S.T. Chiang; Fritz E. Kühn

doi:10.1016/j.jorganchem.2005.10.054

Grafting of η⁵-Cp(COOMe)MoCl(CO)₃ on the surface of mesoporous MCM-41 and MCM-48 materials

Ayyamperumal Sakthivel
, Marta Abrantes
, Anthony S.T. Chiang
, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Technical University of Munich
National Central University

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

η⁵-Cp(COOMe)MoCl(CO)₃ is grafted on the surface of mesoporous MCM-41 and MCM-48 materials through available silanol groups. The structural intactness of the supporting materials is confirmed by powder XRD and N₂ adsorption analysis. The presence of the Mo complex on the surface is confirmed by FT-IR and elemental analysis. The catalysts are successfully applied for cyclooctene epoxidation.

Original language	English
Pages (from-to)	1007-1011
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	5
DOIs	https://doi.org/10.1016/j.jorganchem.2005.10.054
State	Published - 15 Feb 2006

Keywords

Epoxidation
Grafting
Mesoporous materials
Molybdenum
Organometallic complex

Access to Document

10.1016/j.jorganchem.2005.10.054

Cite this

@article{c40f74f04e6647d780932d308d228b9a,

title = "Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials",

abstract = "η5-Cp(COOMe)MoCl(CO)3 is grafted on the surface of mesoporous MCM-41 and MCM-48 materials through available silanol groups. The structural intactness of the supporting materials is confirmed by powder XRD and N2 adsorption analysis. The presence of the Mo complex on the surface is confirmed by FT-IR and elemental analysis. The catalysts are successfully applied for cyclooctene epoxidation.",

keywords = "Epoxidation, Grafting, Mesoporous materials, Molybdenum, Organometallic complex",

author = "Ayyamperumal Sakthivel and Marta Abrantes and Chiang, \{Anthony S.T.\} and K{\"u}hn, \{Fritz E.\}",

year = "2006",

month = feb,

day = "15",

doi = "10.1016/j.jorganchem.2005.10.054",

language = "English",

volume = "691",

pages = "1007--1011",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "5",

}

TY - JOUR

T1 - Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials

AU - Sakthivel, Ayyamperumal

AU - Abrantes, Marta

AU - Chiang, Anthony S.T.

AU - Kühn, Fritz E.

PY - 2006/2/15

Y1 - 2006/2/15

N2 - η5-Cp(COOMe)MoCl(CO)3 is grafted on the surface of mesoporous MCM-41 and MCM-48 materials through available silanol groups. The structural intactness of the supporting materials is confirmed by powder XRD and N2 adsorption analysis. The presence of the Mo complex on the surface is confirmed by FT-IR and elemental analysis. The catalysts are successfully applied for cyclooctene epoxidation.

AB - η5-Cp(COOMe)MoCl(CO)3 is grafted on the surface of mesoporous MCM-41 and MCM-48 materials through available silanol groups. The structural intactness of the supporting materials is confirmed by powder XRD and N2 adsorption analysis. The presence of the Mo complex on the surface is confirmed by FT-IR and elemental analysis. The catalysts are successfully applied for cyclooctene epoxidation.

KW - Epoxidation

KW - Grafting

KW - Mesoporous materials

KW - Molybdenum

KW - Organometallic complex

UR - https://www.scopus.com/pages/publications/31644445689

U2 - 10.1016/j.jorganchem.2005.10.054

DO - 10.1016/j.jorganchem.2005.10.054

M3 - Article

AN - SCOPUS:31644445689

SN - 0022-328X

VL - 691

SP - 1007

EP - 1011

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 5

ER -

Grafting of η⁵-Cp(COOMe)MoCl(CO)₃ on the surface of mesoporous MCM-41 and MCM-48 materials

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this