Gold(I) Complexes of Primary Phosphanes: Pair Formation through Au…Au Interactions

Hubert Schmidbaur, Gabriele Weidenhiller, Oliver Steigelmann, Gerhard Müller

Research output: Contribution to journalComment/debate

56 Scopus citations

Abstract

(CO)AuCl reacts with (2,4,6‐trialkylphenyl)phosphanes 1a–d (alkyl = Me, Et, iPr, tBu) to give the 1:1 complexes 2a–d. The crystal structure of 2d shows pairs of molecules with Au…Au contacts of 3.440(1) Å.

Original languageEnglish
Pages (from-to)285-287
Number of pages3
JournalChemische Berichte
Volume123
Issue number2
DOIs
StatePublished - 1990

Keywords

  • Phosphanes, primary / Gold complexes / Gold–gold interactions

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