Glycosidic Conjugates of Aliphatic Alcohols from Apple Fruit (Malus sylvestris Mill cult. Jonathan)†

Wilfried Schwab; Peter Schreier

doi:10.1021/jf00093a037

Glycosidic Conjugates of Aliphatic Alcohols from Apple Fruit (Malus sylvestris Mill cult. Jonathan)†

Wilfried Schwab, Peter Schreier

University of Würzburg

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

In an extract obtained from neutralized apple juice, cult. Jonathan, by liquid chromatographic separation on Amberlite XAD resin, 2-methylbutyl, hexyl, and 3-hydroxyoctyl β-D-glucopyranoside as well as 2-methylbutyl and hexyl 6-O-α-L-arabinofuranosyl-β-D-glucopyranoside were identified after per-O-methylation by capillary gas chromatography (HRGC) and coupled HRGC techniques, i.e., HRGC-mass spectrometry (HRGC-MS) and HRGC-Fourier transform infrared spectroscopy (HRGC-FTIR). The dissaccharide glycosides were additionally characterized by¹H and¹³C NMR spectroscopies after preparative HPLC of the per-O-methylated glycosidic extracts on silica gel.

Original language	English
Pages (from-to)	757-763
Number of pages	7
Journal	Journal of agricultural and food chemistry
Volume	38
Issue number	3
DOIs	https://doi.org/10.1021/jf00093a037
State	Published - Mar 1990
Externally published	Yes

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title = "Glycosidic Conjugates of Aliphatic Alcohols from Apple Fruit (Malus sylvestris Mill cult. Jonathan)†",

abstract = "In an extract obtained from neutralized apple juice, cult. Jonathan, by liquid chromatographic separation on Amberlite XAD resin, 2-methylbutyl, hexyl, and 3-hydroxyoctyl β-D-glucopyranoside as well as 2-methylbutyl and hexyl 6-O-α-L-arabinofuranosyl-β-D-glucopyranoside were identified after per-O-methylation by capillary gas chromatography (HRGC) and coupled HRGC techniques, i.e., HRGC-mass spectrometry (HRGC-MS) and HRGC-Fourier transform infrared spectroscopy (HRGC-FTIR). The dissaccharide glycosides were additionally characterized by1H and13C NMR spectroscopies after preparative HPLC of the per-O-methylated glycosidic extracts on silica gel.",

author = "Wilfried Schwab and Peter Schreier",

year = "1990",

month = mar,

doi = "10.1021/jf00093a037",

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journal = "Journal of agricultural and food chemistry",

issn = "0021-8561",

publisher = "American Chemical Society",

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T1 - Glycosidic Conjugates of Aliphatic Alcohols from Apple Fruit (Malus sylvestris Mill cult. Jonathan)†

AU - Schwab, Wilfried

AU - Schreier, Peter

PY - 1990/3

Y1 - 1990/3

N2 - In an extract obtained from neutralized apple juice, cult. Jonathan, by liquid chromatographic separation on Amberlite XAD resin, 2-methylbutyl, hexyl, and 3-hydroxyoctyl β-D-glucopyranoside as well as 2-methylbutyl and hexyl 6-O-α-L-arabinofuranosyl-β-D-glucopyranoside were identified after per-O-methylation by capillary gas chromatography (HRGC) and coupled HRGC techniques, i.e., HRGC-mass spectrometry (HRGC-MS) and HRGC-Fourier transform infrared spectroscopy (HRGC-FTIR). The dissaccharide glycosides were additionally characterized by1H and13C NMR spectroscopies after preparative HPLC of the per-O-methylated glycosidic extracts on silica gel.

AB - In an extract obtained from neutralized apple juice, cult. Jonathan, by liquid chromatographic separation on Amberlite XAD resin, 2-methylbutyl, hexyl, and 3-hydroxyoctyl β-D-glucopyranoside as well as 2-methylbutyl and hexyl 6-O-α-L-arabinofuranosyl-β-D-glucopyranoside were identified after per-O-methylation by capillary gas chromatography (HRGC) and coupled HRGC techniques, i.e., HRGC-mass spectrometry (HRGC-MS) and HRGC-Fourier transform infrared spectroscopy (HRGC-FTIR). The dissaccharide glycosides were additionally characterized by1H and13C NMR spectroscopies after preparative HPLC of the per-O-methylated glycosidic extracts on silica gel.

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JF - Journal of agricultural and food chemistry

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ER -

Glycosidic Conjugates of Aliphatic Alcohols from Apple Fruit (Malus sylvestris Mill cult. Jonathan)†

Abstract

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