Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

Ming Fang Cai; Terry A. Miller; V. E. Bondybey

doi:10.1016/0009-2614(89)87373-7

Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

Ming Fang Cai, Terry A. Miller, V. E. Bondybey

Ohio State University

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.

Original language	English
Pages (from-to)	475-479
Number of pages	5
Journal	Chemical Physics Letters
Volume	158
Issue number	6
DOIs	https://doi.org/10.1016/0009-2614(89)87373-7
State	Published - 23 Jun 1989
Externally published	Yes

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title = "Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization",

abstract = "Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.",

author = "Cai, {Ming Fang} and Miller, {Terry A.} and Bondybey, {V. E.}",

note = "Funding Information: The authors gratefullya cknowledget he support of the National ScienceF oundation in this work through grants CHE8803169 (MFC and VEB) and CHE8507537 (TAM).",

year = "1989",

month = jun,

day = "23",

doi = "10.1016/0009-2614(89)87373-7",

language = "English",

volume = "158",

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journal = "Chemical Physics Letters",

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T1 - Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

AU - Cai, Ming Fang

AU - Miller, Terry A.

AU - Bondybey, V. E.

N1 - Funding Information: The authors gratefullya cknowledget he support of the National ScienceF oundation in this work through grants CHE8803169 (MFC and VEB) and CHE8507537 (TAM).

PY - 1989/6/23

Y1 - 1989/6/23

N2 - Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.

AB - Reactive Ba atoms are produced from a Ba rod by YAG laser vaporization in the throat of a seeded He supersonic jet expansion. As the expansion proceeds, the Ba atoms react with the seed gas, benzyl chloride. The reaction products, BaCl and benzyl radical, are observed substantially cooled downstream via laser-induced fluorescence.

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U2 - 10.1016/0009-2614(89)87373-7

DO - 10.1016/0009-2614(89)87373-7

M3 - Article

AN - SCOPUS:4243447226

SN - 0009-2614

VL - 158

SP - 475

EP - 479

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

Generation of cold free radicals by the reaction of organic halides with metal atoms produced by laser vaporization

Abstract

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