Gel-permeation chromatography of solutions of d-glucose after irradiation by ultrasound and γ-rays

Helmut Heusinger

doi:10.1016/0008-6215(91)80149-H

Gel-permeation chromatography of solutions of d-glucose after irradiation by ultrasound and γ-rays

Helmut Heusinger

Radiochemistry Munich

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8 Scopus citations

Abstract

Gel-permeation chromatography on the COO^- and COOH forms of Ultrahydrogel 20 of aqueous solutions of d-glucose irradiated with ultrasound and γ-rays, followed by g.l.c.-m.s. of the trimethylsilylated methoximated derivatives of the products, revealed derivatives of gluconic acid and hexulosonic acids after irradiation in the presence of air and 2-deoxy-arabino-hexonic and gluconic acid after irradiation under argon. A small proportion of products was formed with molecular weights larger than that of glucose and which contained an enolic structure.

Original language	English
Pages (from-to)	109-118
Number of pages	10
Journal	Carbohydrate Research
Volume	209
Issue number	C
DOIs	https://doi.org/10.1016/0008-6215(91)80149-H
State	Published - 15 Jan 1991

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Gel-permeation chromatography of solutions of d-glucose after irradiation by ultrasound and γ-rays

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