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Gas chromatographic enantiomer separation of some selected polycyclic xenobiotics using modified cyclodextrins

  • Technical University of Munich

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The enantiomers of several polychlorinated xenobiotics (heptachlor, cis- and trans-chlordane, trans- and cis-heptachlorepoxide, oxychlordane, photo-heptachlor and photo-heptachlorepoxide, photo-dieldrin, photo-chlordene, α-HCH, o,p'-DDT and o,p'-DDD) have been separated by gas chromatography with three β-cyclodextrin derivatives as chiral selectors. Two of these selectors were dissolved in a polysiloxane stationary phase and one was chemically bonded to a polysiloxane backbone via hydrosilylation. The order of elution of some of the xenobiotics was determined by comparison with enantiomerically enriched reference compounds.

Original languageEnglish
Pages (from-to)489-493
Number of pages5
JournalFresenius Environmental Bulletin
Volume6
Issue number7-8
StatePublished - 1997

Keywords

  • Cyclodextrine derivatives
  • Cyclodiene photoconversion products
  • Enantioselective gas chromatography
  • Polychlorinated pesticides

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