Funktionelle Trimethylphosphanderivate, XV. (Chlormethyl)dimethylphosphan

Hans Heinz Karsch

doi:10.1002/cber.19821150248

Funktionelle Trimethylphosphanderivate, XV. (Chlormethyl)dimethylphosphan

Hans Heinz Karsch

Natural Sciences

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15 Scopus citations

Abstract

Functional Derivatives of Trimethylphosphane, XV. (Chloromethyl)dimethylphosphane (Chloromethyl)dimethylphosphane, Me₂P(CH₂Cl) (3), which is unstable at room temperature, has been synthesized. Reactions with O₂, CH₃Br and LiPMe₂ give Me₂P(O)(CH₂Cl) (4, [Me₃P(CH₂Cl)]Br (5b and Me₂PCH₂PMe₂ (2), respectively. NMR data for these and related compounds are given.

Original language	German
Pages (from-to)	823-827
Number of pages	5
Journal	Chemische Berichte
Volume	115
Issue number	2
DOIs	https://doi.org/10.1002/cber.19821150248
State	Published - 1982

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abstract = "Functional Derivatives of Trimethylphosphane, XV. (Chloromethyl)dimethylphosphane (Chloromethyl)dimethylphosphane, Me2P(CH2Cl) (3), which is unstable at room temperature, has been synthesized. Reactions with O2, CH3Br and LiPMe2 give Me2P(O)(CH2Cl) (4, [Me3P(CH2Cl)]Br (5b and Me2PCH2PMe2 (2), respectively. NMR data for these and related compounds are given.",

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AB - Functional Derivatives of Trimethylphosphane, XV. (Chloromethyl)dimethylphosphane (Chloromethyl)dimethylphosphane, Me2P(CH2Cl) (3), which is unstable at room temperature, has been synthesized. Reactions with O2, CH3Br and LiPMe2 give Me2P(O)(CH2Cl) (4, [Me3P(CH2Cl)]Br (5b and Me2PCH2PMe2 (2), respectively. NMR data for these and related compounds are given.

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Funktionelle Trimethylphosphanderivate, XV. (Chlormethyl)dimethylphosphan

Abstract

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