FT-ICR studies of the reaction of O+ with methanol

Thomas Schindler; Christian Berg; Gereon Niedner-Schatteburg; Vladimir E. Bondybey; Catherine Lugez; Andre Schriver; Louise Schriver

doi:10.1021/j100067a018

FT-ICR studies of the reaction of O⁺ with methanol

Thomas Schindler
, Christian Berg
, Gereon Niedner-Schatteburg
, Vladimir E. Bondybey
, Catherine Lugez
, Andre Schriver
, Louise Schriver

Chair of Physical Chemistry

Technical University of Munich
Centre de Recherche Institut du Cerveau et de la Moelle

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The gas-phase reactions of O⁺ with methanol are investigated by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. Absolute rate constants and branching ratios of the competing reactions are derived. The reaction proceeds mainly via "hydride transfer" yielding CH₃O⁺ product ions. Isotopic studies suggest that both hydroxyl, (OH) and methyl (CH₃) hydrogen atoms are abstracted. Several lighter fragment ion products are also detected. The CH₃O⁺ primary products react efficiently further to yield the protonated methanol ion, CH₃OH₂⁺.

Original language	English
Pages (from-to)	4316-4319
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	98
Issue number	16
DOIs	https://doi.org/10.1021/j100067a018
State	Published - 1994

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title = "FT-ICR studies of the reaction of O+ with methanol",

abstract = "The gas-phase reactions of O+ with methanol are investigated by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. Absolute rate constants and branching ratios of the competing reactions are derived. The reaction proceeds mainly via {"}hydride transfer{"} yielding CH3O+ product ions. Isotopic studies suggest that both hydroxyl, (OH) and methyl (CH3) hydrogen atoms are abstracted. Several lighter fragment ion products are also detected. The CH3O+ primary products react efficiently further to yield the protonated methanol ion, CH3OH2+.",

author = "Thomas Schindler and Christian Berg and Gereon Niedner-Schatteburg and Bondybey, \{Vladimir E.\} and Catherine Lugez and Andre Schriver and Louise Schriver",

year = "1994",

doi = "10.1021/j100067a018",

language = "English",

volume = "98",

pages = "4316--4319",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "16",

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TY - JOUR

T1 - FT-ICR studies of the reaction of O+ with methanol

AU - Schindler, Thomas

AU - Berg, Christian

AU - Niedner-Schatteburg, Gereon

AU - Bondybey, Vladimir E.

AU - Lugez, Catherine

AU - Schriver, Andre

AU - Schriver, Louise

PY - 1994

Y1 - 1994

N2 - The gas-phase reactions of O+ with methanol are investigated by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. Absolute rate constants and branching ratios of the competing reactions are derived. The reaction proceeds mainly via "hydride transfer" yielding CH3O+ product ions. Isotopic studies suggest that both hydroxyl, (OH) and methyl (CH3) hydrogen atoms are abstracted. Several lighter fragment ion products are also detected. The CH3O+ primary products react efficiently further to yield the protonated methanol ion, CH3OH2+.

AB - The gas-phase reactions of O+ with methanol are investigated by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. Absolute rate constants and branching ratios of the competing reactions are derived. The reaction proceeds mainly via "hydride transfer" yielding CH3O+ product ions. Isotopic studies suggest that both hydroxyl, (OH) and methyl (CH3) hydrogen atoms are abstracted. Several lighter fragment ion products are also detected. The CH3O+ primary products react efficiently further to yield the protonated methanol ion, CH3OH2+.

UR - https://www.scopus.com/pages/publications/0041969977

U2 - 10.1021/j100067a018

DO - 10.1021/j100067a018

M3 - Article

AN - SCOPUS:0041969977

SN - 0022-3654

VL - 98

SP - 4316

EP - 4319

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 16

ER -

FT-ICR studies of the reaction of O⁺ with methanol

Abstract

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