Frustrated Lewis pairs: Reactivities of TMS protected amines and phosphines in the presence of B(C6F5)3

Felix Schulz; Victor Sumerin; Markku Leskelä; Timo Repo; Bernhard Rieger

doi:10.1039/b923196j

Frustrated Lewis pairs: Reactivities of TMS protected amines and phosphines in the presence of B(C₆F₅)₃

Felix Schulz, Victor Sumerin, Markku Leskelä, Timo Repo, Bernhard Rieger

Wacker-Chair of Macromolecular Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

TMS protected amines in combination with B(C₆F₅) ₃ were found to activate H₂ and this is followed by a cleavage of the N-Si bond and the generation of TMSH. A TMS protected phosphine on the other hand reacts rapidly with B(C₆F₅)₃ to give the known compound tBu₂P(C₆F₄)B(C ₆F₅)₂ by a facile and efficient route.

Original language	English
Pages (from-to)	1920-1922
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	8
DOIs	https://doi.org/10.1039/b923196j
State	Published - 2010

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title = "Frustrated Lewis pairs: Reactivities of TMS protected amines and phosphines in the presence of B(C6F5)3",

abstract = "TMS protected amines in combination with B(C6F5) 3 were found to activate H2 and this is followed by a cleavage of the N-Si bond and the generation of TMSH. A TMS protected phosphine on the other hand reacts rapidly with B(C6F5)3 to give the known compound tBu2P(C6F4)B(C 6F5)2 by a facile and efficient route.",

author = "Felix Schulz and Victor Sumerin and Markku Leskel{\"a} and Timo Repo and Bernhard Rieger",

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T2 - Reactivities of TMS protected amines and phosphines in the presence of B(C6F5)3

AU - Schulz, Felix

AU - Sumerin, Victor

AU - Leskelä, Markku

AU - Repo, Timo

AU - Rieger, Bernhard

PY - 2010

Y1 - 2010

N2 - TMS protected amines in combination with B(C6F5) 3 were found to activate H2 and this is followed by a cleavage of the N-Si bond and the generation of TMSH. A TMS protected phosphine on the other hand reacts rapidly with B(C6F5)3 to give the known compound tBu2P(C6F4)B(C 6F5)2 by a facile and efficient route.

AB - TMS protected amines in combination with B(C6F5) 3 were found to activate H2 and this is followed by a cleavage of the N-Si bond and the generation of TMSH. A TMS protected phosphine on the other hand reacts rapidly with B(C6F5)3 to give the known compound tBu2P(C6F4)B(C 6F5)2 by a facile and efficient route.

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U2 - 10.1039/b923196j

DO - 10.1039/b923196j

M3 - Article

AN - SCOPUS:76749130115

SN - 1477-9226

VL - 39

SP - 1920

EP - 1922

JO - Dalton Transactions

JF - Dalton Transactions

IS - 8

ER -

Frustrated Lewis pairs: Reactivities of TMS protected amines and phosphines in the presence of B(C₆F₅)₃

Abstract

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