Formation of methyl acrylate from CO2 and ethylene via methylation of nickelalactones

Christian Bruckmeier; Maximilian W. Lehenmeier; Robert Reichardt; Sergei Vagin; Bernhard Rieger

doi:10.1021/om100060y

Formation of methyl acrylate from CO₂ and ethylene via methylation of nickelalactones

Christian Bruckmeier, Maximilian W. Lehenmeier, Robert Reichardt, Sergei Vagin, Bernhard Rieger

Wacker-Chair of Macromolecular Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

107 Scopus citations

Abstract

The nickel-induced coupling of ethylene and CO₂ represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the β-hydride elimination and the liberation of the acrylate species.

Original language	English
Pages (from-to)	2199-2202
Number of pages	4
Journal	Organometallics
Volume	29
Issue number	10
DOIs	https://doi.org/10.1021/om100060y
State	Published - 24 May 2010

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title = "Formation of methyl acrylate from CO2 and ethylene via methylation of nickelalactones",

abstract = "The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the β-hydride elimination and the liberation of the acrylate species.",

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AU - Bruckmeier, Christian

AU - Lehenmeier, Maximilian W.

AU - Reichardt, Robert

AU - Vagin, Sergei

AU - Rieger, Bernhard

PY - 2010/5/24

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N2 - The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the β-hydride elimination and the liberation of the acrylate species.

AB - The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the β-hydride elimination and the liberation of the acrylate species.

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U2 - 10.1021/om100060y

DO - 10.1021/om100060y

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SP - 2199

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JO - Organometallics

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ER -

Formation of methyl acrylate from CO₂ and ethylene via methylation of nickelalactones

Abstract

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