Forbidden electronic transitions of P2 in solid neon

L. A. Heimbrook; M. Rasanen; V. E. Bondybey

doi:10.1016/0009-2614(85)87048-2

Forbidden electronic transitions of P₂ in solid neon

L. A. Heimbrook, M. Rasanen, V. E. Bondybey

Alcatel-Lucent

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10 Scopus citations

Abstract

Several forbidden electronic transitions of P₂ in solid neon are examined. All of the six observed electronic states of P₂ are found to be remarkably unshifted and unperturbed by the matrix. While some absorptions exhibit sharp zero-phonon lines, others are characterized by broad, intense phonon sidebands. This is shown to be a consequence of the orbitally forbidden nature of the corresponding transitions.

Original language	English
Pages (from-to)	233-238
Number of pages	6
Journal	Chemical Physics Letters
Volume	120
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(85)87048-2
State	Published - 11 Oct 1985
Externally published	Yes

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title = "Forbidden electronic transitions of P2 in solid neon",

abstract = "Several forbidden electronic transitions of P2 in solid neon are examined. All of the six observed electronic states of P2 are found to be remarkably unshifted and unperturbed by the matrix. While some absorptions exhibit sharp zero-phonon lines, others are characterized by broad, intense phonon sidebands. This is shown to be a consequence of the orbitally forbidden nature of the corresponding transitions.",

author = "Heimbrook, {L. A.} and M. Rasanen and Bondybey, {V. E.}",

year = "1985",

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T1 - Forbidden electronic transitions of P2 in solid neon

AU - Heimbrook, L. A.

AU - Rasanen, M.

AU - Bondybey, V. E.

PY - 1985/10/11

Y1 - 1985/10/11

N2 - Several forbidden electronic transitions of P2 in solid neon are examined. All of the six observed electronic states of P2 are found to be remarkably unshifted and unperturbed by the matrix. While some absorptions exhibit sharp zero-phonon lines, others are characterized by broad, intense phonon sidebands. This is shown to be a consequence of the orbitally forbidden nature of the corresponding transitions.

AB - Several forbidden electronic transitions of P2 in solid neon are examined. All of the six observed electronic states of P2 are found to be remarkably unshifted and unperturbed by the matrix. While some absorptions exhibit sharp zero-phonon lines, others are characterized by broad, intense phonon sidebands. This is shown to be a consequence of the orbitally forbidden nature of the corresponding transitions.

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U2 - 10.1016/0009-2614(85)87048-2

DO - 10.1016/0009-2614(85)87048-2

M3 - Article

AN - SCOPUS:46549091131

SN - 0009-2614

VL - 120

SP - 233

EP - 238

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Forbidden electronic transitions of P₂ in solid neon

Abstract

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