Fluxional behavior of indenyl-derived ytterbocene (II) complexes. The SiHR2 group as a NMR spectroscopic probe

Michael G. Klimpel; Wolfgang A. Herrmann; Reiner Anwander

doi:10.1021/om000324w

Fluxional behavior of indenyl-derived ytterbocene (II) complexes. The SiHR₂ group as a NMR spectroscopic probe

Michael G. Klimpel
, Wolfgang A. Herrmann
, Reiner Anwander

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Indenyl-derived ytterbocene(II) complexes [1-(SiHR₂)-2-R′-C₉H₅] ₂Yb(L)₂ (R = Me, C₆H₅; R′ = H, Me; L = donor ligand) have been synthesized via silylamine elimination from Yb[N(SiMe₃)₂]₂(THF)₂ and the indene derivatives in hexane at ambient temperature.

Original language	English
Pages (from-to)	4666-4668
Number of pages	3
Journal	Organometallics
Volume	19
Issue number	23
DOIs	https://doi.org/10.1021/om000324w
State	Published - 13 Nov 2000

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title = "Fluxional behavior of indenyl-derived ytterbocene (II) complexes. The SiHR2 group as a NMR spectroscopic probe",

abstract = "Indenyl-derived ytterbocene(II) complexes [1-(SiHR2)-2-R′-C9H5] 2Yb(L)2 (R = Me, C6H5; R′ = H, Me; L = donor ligand) have been synthesized via silylamine elimination from Yb[N(SiMe3)2]2(THF)2 and the indene derivatives in hexane at ambient temperature.",

author = "Klimpel, \{Michael G.\} and Herrmann, \{Wolfgang A.\} and Reiner Anwander",

year = "2000",

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journal = "Organometallics",

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T1 - Fluxional behavior of indenyl-derived ytterbocene (II) complexes. The SiHR2 group as a NMR spectroscopic probe

AU - Klimpel, Michael G.

AU - Herrmann, Wolfgang A.

AU - Anwander, Reiner

PY - 2000/11/13

Y1 - 2000/11/13

N2 - Indenyl-derived ytterbocene(II) complexes [1-(SiHR2)-2-R′-C9H5] 2Yb(L)2 (R = Me, C6H5; R′ = H, Me; L = donor ligand) have been synthesized via silylamine elimination from Yb[N(SiMe3)2]2(THF)2 and the indene derivatives in hexane at ambient temperature.

AB - Indenyl-derived ytterbocene(II) complexes [1-(SiHR2)-2-R′-C9H5] 2Yb(L)2 (R = Me, C6H5; R′ = H, Me; L = donor ligand) have been synthesized via silylamine elimination from Yb[N(SiMe3)2]2(THF)2 and the indene derivatives in hexane at ambient temperature.

UR - https://www.scopus.com/pages/publications/0034319290

U2 - 10.1021/om000324w

DO - 10.1021/om000324w

M3 - Article

AN - SCOPUS:0034319290

SN - 0276-7333

VL - 19

SP - 4666

EP - 4668

JO - Organometallics

JF - Organometallics

IS - 23

ER -

Fluxional behavior of indenyl-derived ytterbocene (II) complexes. The SiHR₂ group as a NMR spectroscopic probe

Abstract

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