TY - JOUR
T1 - Fluorescence spectroscopy of supersonically cooled CFCI
AU - Schlachta, Richard
AU - Lask, Gerrit M.
AU - Bondybey, Vladimir E.
PY - 1991
Y1 - 1991
N2 - The spectra of the cold chlorofluorocarbene, CFCI, were generated using a technique combinining d.c. discharge with pulsed supersonic expansion and with laser-induced fluorescence detection of the products. The fluorescence excitation spectra were recorded using a pulsed, tunable dye laser and were analysed. Information about the structure was obtained by comparing the experimental rotational contours with the simulated band profiles. The obtained spectroscopic constants and structural parameters are summarized and compared with the previously available data and with the theoretical predictions.
AB - The spectra of the cold chlorofluorocarbene, CFCI, were generated using a technique combinining d.c. discharge with pulsed supersonic expansion and with laser-induced fluorescence detection of the products. The fluorescence excitation spectra were recorded using a pulsed, tunable dye laser and were analysed. Information about the structure was obtained by comparing the experimental rotational contours with the simulated band profiles. The obtained spectroscopic constants and structural parameters are summarized and compared with the previously available data and with the theoretical predictions.
UR - http://www.scopus.com/inward/record.url?scp=0007705055&partnerID=8YFLogxK
U2 - 10.1039/FT9918702407
DO - 10.1039/FT9918702407
M3 - Article
AN - SCOPUS:0007705055
SN - 0956-5000
VL - 87
SP - 2407
EP - 2412
JO - Journal of the Chemical Society, Faraday Transactions
JF - Journal of the Chemical Society, Faraday Transactions
IS - 15
ER -