First synthesis and structural determination of blepharin and 1'-epiblepharin

L. F. Tietze, M. Beller, A. Terfort, A. Dolle

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

Total synthesis of the natural acetal-β-D-glucoside blepharin (1) and its C-2, epimer 9 by treatment of 2-bromo-2H-1,4-benzoxazin-3(4H)-one (5) with 2,3,4,6-tetra-O-acetyl-β-D-glucopyranose (6) is described. The relative and absolute configuration of 1 was determined by 1H-NMR and X-ray analysis.

Original languageEnglish
Pages (from-to)1118-1120
Number of pages3
JournalSynthesis
Issue number12
DOIs
StatePublished - 1991
Externally publishedYes

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