TY - JOUR
T1 - First and second law of quantum thermodynamics
T2 - A consistent derivation based on a microscopic definition of entropy
AU - Strasberg, Philipp
AU - Winter, Andreas
N1 - Publisher Copyright:
© 2021 authors. Published by the American Physical Society. Published by the American Physical Society under the terms of the "https://creativecommons.org/licenses/by/4.0/"Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.
PY - 2021/9
Y1 - 2021/9
N2 - Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for isolated and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies. The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat, and temperature. These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of states and processes. The consistency with previous results is demonstrated. The framework applies to multiple baths including particle transport and accounts for processes with, e.g., a changing temperature of the bath, which is determined microscopically. An integral fluctuation theorem for entropy production is satisfied. In summary, this tutorial introduces a consistent and versatile framework to understand and apply the laws of thermodynamics in the quantum regime and beyond.
AB - Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for isolated and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies. The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat, and temperature. These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of states and processes. The consistency with previous results is demonstrated. The framework applies to multiple baths including particle transport and accounts for processes with, e.g., a changing temperature of the bath, which is determined microscopically. An integral fluctuation theorem for entropy production is satisfied. In summary, this tutorial introduces a consistent and versatile framework to understand and apply the laws of thermodynamics in the quantum regime and beyond.
UR - http://www.scopus.com/inward/record.url?scp=85116388701&partnerID=8YFLogxK
U2 - 10.1103/PRXQuantum.2.030202
DO - 10.1103/PRXQuantum.2.030202
M3 - Article
AN - SCOPUS:85116388701
SN - 2691-3399
VL - 2
JO - PRX Quantum
JF - PRX Quantum
IS - 3
M1 - 030202
ER -