Abstract
Treatment of bis(diphenylphosphino)amine (dppa) with (dimethylsulfide)gold(I) chloride in the molar ratio 1:2 leads to the dinuclear complex (dppa)Au2Cl2 in 95% yield. The compound was crystallized from diethyl ether/dimethylformamide as the 1:1 solvate with dmf, the crystal structure of which has been determined. The complex features an intramolecular Au-Au contact [3.121(1) Å] and an intermolecular hydrogen bond NH-O=C.
| Original language | English |
|---|---|
| Pages (from-to) | 769-771 |
| Number of pages | 3 |
| Journal | Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences |
| Volume | 52 |
| Issue number | 6 |
| DOIs | |
| State | Published - Jun 1997 |
Keywords
- Bis(diphenylphosphino)-amine Complexes
- Gold(I) Chloride Complex
- Gold(I) Complexes
- Phosphine Complex