TY - JOUR
T1 - Exhaustive Oxidative Decarbonylation of Metal Carbonyls by Light and Oxygen
T2 - The Example of (η5‐C5Me5)ReO3
AU - Herrmann, Wolfgang A.
AU - Serrano, Ricardo
AU - Bock, Hans
PY - 1984/5
Y1 - 1984/5
N2 - The trioxorhenium complex 3—lemon yellow, air‐stable, crystalline—is surprisingly formed on photolysis of the tricarbonylrhenium complex 1 in THF. In complete absence of oxygen the initial product is 2, which (unlike analogous manganese complexes) is oxidized by air to 3. (Figure Presented.)
AB - The trioxorhenium complex 3—lemon yellow, air‐stable, crystalline—is surprisingly formed on photolysis of the tricarbonylrhenium complex 1 in THF. In complete absence of oxygen the initial product is 2, which (unlike analogous manganese complexes) is oxidized by air to 3. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985570388&partnerID=8YFLogxK
U2 - 10.1002/anie.198403831
DO - 10.1002/anie.198403831
M3 - Article
AN - SCOPUS:84985570388
SN - 0570-0833
VL - 23
SP - 383
EP - 385
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 5
ER -