Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

Nina Fechler; Niels P. Zussblatt; Regina Rothe; Robert Schlögl; Marc Georg Willinger; Bradley F. Chmelka; Markus Antonietti

doi:10.1002/adma.201501503

Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

Nina Fechler, Niels P. Zussblatt, Regina Rothe, Robert Schlögl, Marc Georg Willinger, Bradley F. Chmelka, Markus Antonietti

Research output: Contribution to journal › Article › peer-review

89 Scopus citations

Abstract

Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid-crystalline-like phases that can be processed. The architecture of phenol/ketone acts as structure-donating motif, while urea serves as melting-point reduction agent. Condensation at elevated temperatures results in nitrogen-containing carbons with remarkably high nitrogen content of mainly pyrazinic nature.

Original language	English
Pages (from-to)	1287-1294
Number of pages	8
Journal	Advanced Materials
Volume	28
Issue number	6
DOIs	https://doi.org/10.1002/adma.201501503
State	Published - 10 Feb 2016
Externally published	Yes

Keywords

deep eutectic mixtures
liquid crystals
porous materials
pyrazinic nitrogen-containing carbon
self-assembly

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10.1002/adma.201501503

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title = "Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content",

abstract = "Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid-crystalline-like phases that can be processed. The architecture of phenol/ketone acts as structure-donating motif, while urea serves as melting-point reduction agent. Condensation at elevated temperatures results in nitrogen-containing carbons with remarkably high nitrogen content of mainly pyrazinic nature.",

keywords = "deep eutectic mixtures, liquid crystals, porous materials, pyrazinic nitrogen-containing carbon, self-assembly",

author = "Nina Fechler and Zussblatt, {Niels P.} and Regina Rothe and Robert Schl{\"o}gl and Willinger, {Marc Georg} and Chmelka, {Bradley F.} and Markus Antonietti",

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AU - Fechler, Nina

AU - Zussblatt, Niels P.

AU - Rothe, Regina

AU - Schlögl, Robert

AU - Willinger, Marc Georg

AU - Chmelka, Bradley F.

AU - Antonietti, Markus

PY - 2016/2/10

Y1 - 2016/2/10

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AB - Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid-crystalline-like phases that can be processed. The architecture of phenol/ketone acts as structure-donating motif, while urea serves as melting-point reduction agent. Condensation at elevated temperatures results in nitrogen-containing carbons with remarkably high nitrogen content of mainly pyrazinic nature.

KW - deep eutectic mixtures

KW - liquid crystals

KW - porous materials

KW - pyrazinic nitrogen-containing carbon

KW - self-assembly

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JO - Advanced Materials

JF - Advanced Materials

IS - 6

ER -

Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

Abstract

Keywords

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