TY - JOUR
T1 - Epoxidation in ionic liquids
T2 - A comparison of rhenium(VII) and molybdenum(VI) catalysts
AU - Betz, Daniel
AU - Herrmann, Wolfgang A.
AU - Kühn, Fritz E.
PY - 2009/9/15
Y1 - 2009/9/15
N2 - Complexes of the type (dimethyl-bpy)MoO2Cl2 and Schiff/Lewis-base complexes of methyltrioxorhenium (MTO), being efficient homogeneous catalysts for the epoxidation of olefins, have been examined with respect to their catalytic performance at 55 and 25 °C in systems employing room temperature ionic liquids (RTILs) of composition [BMIM]NTf2, [BMIM]PF6, [BMIM]BF4 and [C8MIM]PF6 as solvents. The performance in the cyclooctene epoxidation was observed to be strongly dependent on the water content of the system and the catalyst solubility in the RTIL. MTO based systems prove to be superior with respect to lower energy consumption, higher stability and higher product yields compared to the investigated Mo(VI) system under the conditions applied.
AB - Complexes of the type (dimethyl-bpy)MoO2Cl2 and Schiff/Lewis-base complexes of methyltrioxorhenium (MTO), being efficient homogeneous catalysts for the epoxidation of olefins, have been examined with respect to their catalytic performance at 55 and 25 °C in systems employing room temperature ionic liquids (RTILs) of composition [BMIM]NTf2, [BMIM]PF6, [BMIM]BF4 and [C8MIM]PF6 as solvents. The performance in the cyclooctene epoxidation was observed to be strongly dependent on the water content of the system and the catalyst solubility in the RTIL. MTO based systems prove to be superior with respect to lower energy consumption, higher stability and higher product yields compared to the investigated Mo(VI) system under the conditions applied.
KW - Catalysis
KW - Ionic liquids
KW - Methyltrioxorhenium
KW - Molybdenum
KW - Olefin epoxidation
UR - http://www.scopus.com/inward/record.url?scp=68549126883&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2009.06.004
DO - 10.1016/j.jorganchem.2009.06.004
M3 - Article
AN - SCOPUS:68549126883
SN - 0022-328X
VL - 694
SP - 3320
EP - 3324
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 20
ER -
