Energetics of the Splitting of Pyrimidine Photodimers Induced by Electron Transfer to Rhodium(III) Complexes. A Quantum Chemical Study

Keyphrases

• Pyrimidine 100%
• Electron Transfer 100%
• Quantum Chemistry 100%
• Rhodium(III) Complex 100%
• Rh(III) 100%
• Photodimer 100%
• Environmental Impact 40%
• Rh Complex 40%
• Photorepair 40%
• Medium Size 20%
• Thermodynamics 20%
• Cyclobutane 20%
• Whole Systems 20%
• Reaction Cycle 20%
• Diimine 20%
• 4,4′-Dimethyl-2,2′-bipyridine 20%
• Electron Holes 20%
• Quantum Chemical Calculations 20%
• Radical Cation 20%
• First Excited State 20%
• Electron Transfer Reaction 20%
• Excitation Energy 20%
• Charge-transfer Character 20%
• B3LYP 20%
• 9,10-anthraquinone 20%
• Hybrid Density Functional Calculations 20%
• Polar Environment 20%
• Phenantrene 20%
• Intraligand Charge Transfer 20%
• Dinner 20%
• Back Electron Transfer 20%
• Thermal Electron Transfer 20%

Chemistry

• Rhodium 100%
• Energetics 100%
• Electron Transport 100%
• DNA 42%
• Bipyridine 14%
• Ammonia 14%
• Excited State 14%
• Quantum Chemical Calculations 14%
• Radical Cation 14%
• ZINDO Calculation 14%
• DFT-B3LYP Calculation 14%
• Hole (Electron) 14%
• Cyclobutane 14%
• Excitation System 14%