TY - JOUR
T1 - Enantiopure metal-organic framework thin films
T2 - Oriented SURMOF growth and enantioselective adsorption
AU - Liu, Bo
AU - Shekhah, Osama
AU - Arslan, Hasan K.
AU - Liu, Jinxuan
AU - Wöll, Christof
AU - Fischer, Roland A.
PY - 2012/1/16
Y1 - 2012/1/16
N2 - Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn 2((+)cam) 2(dabco)} n] ((+)cam=(1R,3S)-(+)- camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal-organic frameworks (SURMOF) [Zn 2((±)cam) 2(dabco)] pairs can be demonstrated (see picture).
AB - Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn 2((+)cam) 2(dabco)} n] ((+)cam=(1R,3S)-(+)- camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal-organic frameworks (SURMOF) [Zn 2((±)cam) 2(dabco)] pairs can be demonstrated (see picture).
KW - enantiopure metal-organic frameworks
KW - enantioselective adsorption
KW - quartz crystal microbalance
KW - surface chemistry
KW - thin films
UR - http://www.scopus.com/inward/record.url?scp=84862908061&partnerID=8YFLogxK
U2 - 10.1002/anie.201104240
DO - 10.1002/anie.201104240
M3 - Article
AN - SCOPUS:84862908061
SN - 1433-7851
VL - 51
SP - 807
EP - 810
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 3
ER -