Enantiodivergent Photochemical Rearrangements Due to Different Coordination Modes at an Oxazaborolidine Lewis Acid Catalyst

Keyphrases

• Coordination Modes 100%
• Different Coordination 100%
• Lewis Acid Catalyst 100%
• Oxazaborolidine 100%
• Photochemical Rearrangement 100%
• Enantiodivergent 100%
• Substrate Binding 66%
• Stereochemical Hypothesis 66%
• Methane 33%
• Bulky Substituents 33%
• Density Functional Theory 33%
• Enantioselectivity 33%
• Excited States 33%
• Product Formation 33%
• Absolute Configuration 33%
• Conical Intersection 33%
• Excess Energy 33%
• Time-dependent Density Functional Theory 33%
• Substrate Complexity 33%
• Enantiomeric 33%
• Cyclohexadienones 33%
• Catalyst Substrate 33%
• Library Screening 33%
• Concave Side 33%
• Catalyst Libraries 33%
• Enantiodivergence 33%

Chemistry

• Lewis Acid 100%
• Acid Catalyst 100%
• Ground State 50%
• Methane 50%
• Enantioselectivity 50%
• Excited State 50%
• Absolute Configuration 50%
• formation 50%
• Enantiomer 50%
• Density Functional Theory 50%