Emission and excitation spectra of the CCN free radical in solid argon

V. E. Bondybey; J. H. English

doi:10.1016/0022-2852(78)90158-3

Emission and excitation spectra of the CCN free radical in solid argon

V. E. Bondybey, J. H. English

Alcatel-Lucent

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

We demonstrate that 1216 Å photolysis of acetonitrile in rare gas solids leads to efficient production of the CCN free radicals. These radicals emit in solid Ar with a 170 ns lifetime. Study of the A²Δ_i → X²Π_i emission spectra provides values of 1066 and 1717 cm^-1, respectively, for the ground state stretching frequencies. Several weaker vibronic bands are interpreted in terms of the bending fundamentals ν′₂ and ν″₂.

Original language	English
Pages (from-to)	236-242
Number of pages	7
Journal	Journal of Molecular Spectroscopy
Volume	70
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(78)90158-3
State	Published - May 1978
Externally published	Yes

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10.1016/0022-2852(78)90158-3

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title = "Emission and excitation spectra of the CCN free radical in solid argon",

abstract = "We demonstrate that 1216 {\AA} photolysis of acetonitrile in rare gas solids leads to efficient production of the CCN free radicals. These radicals emit in solid Ar with a 170 ns lifetime. Study of the A2Δi → X2Πi emission spectra provides values of 1066 and 1717 cm-1, respectively, for the ground state stretching frequencies. Several weaker vibronic bands are interpreted in terms of the bending fundamentals ν′2 and ν″2.",

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AU - Bondybey, V. E.

AU - English, J. H.

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N2 - We demonstrate that 1216 Å photolysis of acetonitrile in rare gas solids leads to efficient production of the CCN free radicals. These radicals emit in solid Ar with a 170 ns lifetime. Study of the A2Δi → X2Πi emission spectra provides values of 1066 and 1717 cm-1, respectively, for the ground state stretching frequencies. Several weaker vibronic bands are interpreted in terms of the bending fundamentals ν′2 and ν″2.

AB - We demonstrate that 1216 Å photolysis of acetonitrile in rare gas solids leads to efficient production of the CCN free radicals. These radicals emit in solid Ar with a 170 ns lifetime. Study of the A2Δi → X2Πi emission spectra provides values of 1066 and 1717 cm-1, respectively, for the ground state stretching frequencies. Several weaker vibronic bands are interpreted in terms of the bending fundamentals ν′2 and ν″2.

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U2 - 10.1016/0022-2852(78)90158-3

DO - 10.1016/0022-2852(78)90158-3

M3 - Article

AN - SCOPUS:0001315390

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VL - 70

SP - 236

EP - 242

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

IS - 2

ER -

Emission and excitation spectra of the CCN free radical in solid argon

Abstract

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