Emission and excitation spectra of CCl2 in solid argon

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Abstract

Studies of the CCl2 excitation spectra in solid argon give values of 624 and 304 cm-1 for the upper-state vibrational modes ν1 and ν2, respectively. The 000-000 band of the electronic transition occurs at 17 092 cm-1. Vibrational relaxation in the upper state is fast compared with the 3.6 μsec emission lifetime, and only vibrationally relaxed emission is observed.

Original languageEnglish
Pages (from-to)180-183
Number of pages4
JournalJournal of Molecular Spectroscopy
Volume64
Issue number2
DOIs
StatePublished - Feb 1977
Externally publishedYes

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