@article{1d2ed14965074b4293f5baf059a0bb3f,
title = "Electronic structure of Re2Cl82-",
abstract = "The multiple scattering Xα method has been used to calculate the ordering of both occupied and unoccupied one-electron energy states of Re3Cl82-. Single crystal polarized electronic spectra of [(n-C4H9)4N]2[Re2Cl8] have been measured at 5 K. Principal band maxima are observed at 14 180 (z), 30870 (xy), and 39 215 (z) cm-1. The calculation, observed polarizations, and a comparison of band positions in Re2Cl82- and Re2Br82- suggest the following transition assignments for the former complex: 14 180 cm-1, b2gδ → b1uδ*; 30 870 cm-1, eg → b1uδ*; 39 215 cm-1, euπ → egπ*.",
author = "Mortola, {Albert P.} and Moskowitz, {Jules W.} and Notker Rosch and Cowman, {Charles D.} and Gray, {Harry B.}",
note = "Funding Information: Tke .&hors acknoivlddge the ti A.&C. ccm; jiut@qjce,nteq {\textquoteright} for a generous g&t cf &z-iput&{\textquoteleft}time. W! $jank JoI~{\textquoteleft}Ca~a~y &!{\textquoteleft}Johsj Wood fez a&~+-,_i{\textquoteleft}ng us tb use their cotipuier programs. Research at{\textquoteright} 1:{\textquoteright} Nyo,&zq addit$onaIly supported by the National {\textquoteleft}:: S&nce Fdundation (GP-10331) and by@ Deutsche ,I.{\textquoteright} ,~orschungsge,meinscflaftl Research at t1le~CaJiforn.k 1{\textquoteright} Institut& of-Tec&ologLwas supported by the A&r.{\textquoteleft}_.",
year = "1975",
month = apr,
day = "15",
doi = "10.1016/0009-2614(75)85125-6",
language = "English",
volume = "32",
pages = "283--286",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier B.V.",
number = "2",
}