Electronic structure of diatomic boron carbide

Alice M. Smith; Martin Lorenz; Jürgen Agreiter; Vladimir E. Bondybey

doi:10.1080/00268979650026721

Electronic structure of diatomic boron carbide

Alice M. Smith
, Martin Lorenz
, Jürgen Agreiter
, Vladimir E. Bondybey

Chair of Physical Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Products of simultaneous laser vaporization of boron and carbon solids are trapped in solid neon at 6 K and absorption and laser-induced emission bands due to diatomic BC are observed through Fourier-transform spectroscopy. The vibrational constants for five of its low-lying states, (X⁴Σ^-, A⁴Π, B⁴Σ^-, a²Π and d²Σ⁺) are reported for the first time, and the results compared with the thorough theoretical calculations of Hirsch and Buenker.

Original language	English
Pages (from-to)	247-254
Number of pages	8
Journal	Molecular Physics
Volume	88
Issue number	1
DOIs	https://doi.org/10.1080/00268979650026721
State	Published - 1996

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title = "Electronic structure of diatomic boron carbide",

abstract = "Products of simultaneous laser vaporization of boron and carbon solids are trapped in solid neon at 6 K and absorption and laser-induced emission bands due to diatomic BC are observed through Fourier-transform spectroscopy. The vibrational constants for five of its low-lying states, (X4Σ-, A4Π, B4Σ-, a2Π and d2Σ+) are reported for the first time, and the results compared with the thorough theoretical calculations of Hirsch and Buenker.",

author = "Smith, \{Alice M.\} and Martin Lorenz and J{\"u}rgen Agreiter and Bondybey, \{Vladimir E.\}",

note = "Funding Information: Thanks are due to Peter Ka\$ mmerer for the pellet preparation and other technical assistance. Financial support for this research provided by the Deutsche Fors-chungsgemeinschaft and the Fonds der Chemischen Industries is gratefully acknowledged.",

year = "1996",

doi = "10.1080/00268979650026721",

language = "English",

volume = "88",

pages = "247--254",

journal = "Molecular Physics",

issn = "0026-8976",

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TY - JOUR

T1 - Electronic structure of diatomic boron carbide

AU - Smith, Alice M.

AU - Lorenz, Martin

AU - Agreiter, Jürgen

AU - Bondybey, Vladimir E.

N1 - Funding Information: Thanks are due to Peter Ka$ mmerer for the pellet preparation and other technical assistance. Financial support for this research provided by the Deutsche Fors-chungsgemeinschaft and the Fonds der Chemischen Industries is gratefully acknowledged.

PY - 1996

Y1 - 1996

N2 - Products of simultaneous laser vaporization of boron and carbon solids are trapped in solid neon at 6 K and absorption and laser-induced emission bands due to diatomic BC are observed through Fourier-transform spectroscopy. The vibrational constants for five of its low-lying states, (X4Σ-, A4Π, B4Σ-, a2Π and d2Σ+) are reported for the first time, and the results compared with the thorough theoretical calculations of Hirsch and Buenker.

AB - Products of simultaneous laser vaporization of boron and carbon solids are trapped in solid neon at 6 K and absorption and laser-induced emission bands due to diatomic BC are observed through Fourier-transform spectroscopy. The vibrational constants for five of its low-lying states, (X4Σ-, A4Π, B4Σ-, a2Π and d2Σ+) are reported for the first time, and the results compared with the thorough theoretical calculations of Hirsch and Buenker.

UR - https://www.scopus.com/pages/publications/0011628741

U2 - 10.1080/00268979650026721

DO - 10.1080/00268979650026721

M3 - Article

AN - SCOPUS:0011628741

SN - 0026-8976

VL - 88

SP - 247

EP - 254

JO - Molecular Physics

JF - Molecular Physics

IS - 1

ER -

Electronic structure of diatomic boron carbide

Abstract

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