Electronic structure and vibrational frequency of Cr2

V. E. Bondybey; J. H. English

doi:10.1016/0009-2614(83)85029-5

Electronic structure and vibrational frequency of Cr₂

V. E. Bondybey, J. H. English

Alcatel-Lucent

Research output: Contribution to journal › Article › peer-review

215 Scopus citations

Abstract

Cr₂ is produced by pulsed YAG laser vaporization of chromium metal and its fluorescence excitation spectrum is analyzed. The high value of vibrational frequency ΔG″_{1 2} = 452.34 cm^-I (ω″^e ≈ 470 cm^-1) and short internuclear distance r″_e = 1.6788 Å are indicative of a very strongly bound ¹∑⁺_g ground state.

Original language	English
Pages (from-to)	443-447
Number of pages	5
Journal	Chemical Physics Letters
Volume	94
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(83)85029-5
State	Published - 4 Feb 1983
Externally published	Yes

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@article{cd2ebe8bd4cf44dda0e4637bc12eec6a,

title = "Electronic structure and vibrational frequency of Cr2",

abstract = "Cr2 is produced by pulsed YAG laser vaporization of chromium metal and its fluorescence excitation spectrum is analyzed. The high value of vibrational frequency ΔG″ 1 2 = 452.34 cm-I (ω″e ≈ 470 cm-1) and short internuclear distance r″e = 1.6788 {\AA} are indicative of a very strongly bound 1∑+g ground state.",

author = "Bondybey, {V. E.} and English, {J. H.}",

year = "1983",

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T1 - Electronic structure and vibrational frequency of Cr2

AU - Bondybey, V. E.

AU - English, J. H.

PY - 1983/2/4

Y1 - 1983/2/4

N2 - Cr2 is produced by pulsed YAG laser vaporization of chromium metal and its fluorescence excitation spectrum is analyzed. The high value of vibrational frequency ΔG″ 1 2 = 452.34 cm-I (ω″e ≈ 470 cm-1) and short internuclear distance r″e = 1.6788 Å are indicative of a very strongly bound 1∑+g ground state.

AB - Cr2 is produced by pulsed YAG laser vaporization of chromium metal and its fluorescence excitation spectrum is analyzed. The high value of vibrational frequency ΔG″ 1 2 = 452.34 cm-I (ω″e ≈ 470 cm-1) and short internuclear distance r″e = 1.6788 Å are indicative of a very strongly bound 1∑+g ground state.

UR - http://www.scopus.com/inward/record.url?scp=0001214629&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(83)85029-5

DO - 10.1016/0009-2614(83)85029-5

M3 - Article

AN - SCOPUS:0001214629

SN - 0009-2614

VL - 94

SP - 443

EP - 447

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5

ER -

Electronic structure and vibrational frequency of Cr₂

Abstract

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