Electronic structure and spectra of SnBi

V. E. Bondybey; J. H. English

doi:10.1063/1.445617

Electronic structure and spectra of SnBi

V. E. Bondybey
, J. H. English

Alcatel-Lucent

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

An electronic transition with origin near 16 445 cm^-1 is observed in vapor produced by YAG laser vaporization of an alloy of tin and bismuth and assigned to SnBi diatomic. Vibrational analysis yields vibrational frequencies ω″_e=183.06 and ω′_e= 127.6 5cm^-1. A preliminary rotational analysis gives r″_e ∼2.612 Å and r′_e ∼2.814 Å. The observed transition is interpreted in terms of SnBi electronic structure, and bonding in heavy metal diatomics is discussed.

Original language	English
Pages (from-to)	4746-4748
Number of pages	3
Journal	Journal of Chemical Physics
Volume	79
Issue number	10
DOIs	https://doi.org/10.1063/1.445617
State	Published - 1983
Externally published	Yes

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10.1063/1.445617

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@article{354cd069fac5447bb09cd84267fff59c,

title = "Electronic structure and spectra of SnBi",

abstract = "An electronic transition with origin near 16 445 cm-1 is observed in vapor produced by YAG laser vaporization of an alloy of tin and bismuth and assigned to SnBi diatomic. Vibrational analysis yields vibrational frequencies ω″e=183.06 and ω′e= 127.6 5cm-1. A preliminary rotational analysis gives r″e ∼2.612 {\AA} and r′e ∼2.814 {\AA}. The observed transition is interpreted in terms of SnBi electronic structure, and bonding in heavy metal diatomics is discussed.",

author = "Bondybey, \{V. E.\} and English, \{J. H.\}",

year = "1983",

doi = "10.1063/1.445617",

language = "English",

volume = "79",

pages = "4746--4748",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

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TY - JOUR

T1 - Electronic structure and spectra of SnBi

AU - Bondybey, V. E.

AU - English, J. H.

PY - 1983

Y1 - 1983

N2 - An electronic transition with origin near 16 445 cm-1 is observed in vapor produced by YAG laser vaporization of an alloy of tin and bismuth and assigned to SnBi diatomic. Vibrational analysis yields vibrational frequencies ω″e=183.06 and ω′e= 127.6 5cm-1. A preliminary rotational analysis gives r″e ∼2.612 Å and r′e ∼2.814 Å. The observed transition is interpreted in terms of SnBi electronic structure, and bonding in heavy metal diatomics is discussed.

AB - An electronic transition with origin near 16 445 cm-1 is observed in vapor produced by YAG laser vaporization of an alloy of tin and bismuth and assigned to SnBi diatomic. Vibrational analysis yields vibrational frequencies ω″e=183.06 and ω′e= 127.6 5cm-1. A preliminary rotational analysis gives r″e ∼2.612 Å and r′e ∼2.814 Å. The observed transition is interpreted in terms of SnBi electronic structure, and bonding in heavy metal diatomics is discussed.

UR - https://www.scopus.com/pages/publications/0001284905

U2 - 10.1063/1.445617

DO - 10.1063/1.445617

M3 - Article

AN - SCOPUS:0001284905

SN - 0021-9606

VL - 79

SP - 4746

EP - 4748

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 10

ER -

Electronic structure and spectra of SnBi

Abstract

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