Electron scattering in cooled HCl: boomerang structures and outer-well resonances in elastic and vibrational excitation cross sections

Michael Allan, Martin Čížek, Jiří Horáček, Wolfgang Domcke

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Abstract

Differential cross sections for elastic scattering and excitation of the v = 1 vibrational level have been measured for rotationally cooled HCl at energies near the threshold for dissociative attachment. The cooling improves the visibility of the oscillatory structure in the v = 0 → 1 cross section and permits the observation of a similar structure also in the elastic channel. The integral v = 0 → 1 cross section and the resonant part of the integral elastic cross section have been calculated using a nonlocal resonance model. A high degree of agreement of the details of the measured and calculated structures confirms the correctness of the model and the high accuracy of the ab initio HCl- potential-energy function used as input to the model.

Original languageEnglish
Pages (from-to)L209-L213
JournalJournal of Physics B: Atomic, Molecular and Optical Physics
Volume33
Issue number6
DOIs
StatePublished - 28 Mar 2000

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