TY - JOUR
T1 - Elaboration of a Highly Porous RuII,II Analogue of HKUST-1
AU - Zhang, Wenhua
AU - Freitag, Kerstin
AU - Wannapaiboon, Suttipong
AU - Schneider, Christian
AU - Epp, Konstantin
AU - Kieslich, Gregor
AU - Fischer, Roland A.
N1 - Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/12/19
Y1 - 2016/12/19
N2 - When the dinuclear RuII,II precursor [Ru2(OOCCH3)4] is employed under redox-inert conditions, a RuII,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m2/mmol of RuII,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m2/ mmol).
AB - When the dinuclear RuII,II precursor [Ru2(OOCCH3)4] is employed under redox-inert conditions, a RuII,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m2/mmol of RuII,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m2/ mmol).
UR - http://www.scopus.com/inward/record.url?scp=85006736349&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.6b02038
DO - 10.1021/acs.inorgchem.6b02038
M3 - Article
AN - SCOPUS:85006736349
SN - 0020-1669
VL - 55
SP - 12492
EP - 12495
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 24
ER -