Elaboration of a Highly Porous RuII,II Analogue of HKUST-1

Wenhua Zhang, Kerstin Freitag, Suttipong Wannapaiboon, Christian Schneider, Konstantin Epp, Gregor Kieslich, Roland A. Fischer

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17 Scopus citations

Abstract

When the dinuclear RuII,II precursor [Ru2(OOCCH3)4] is employed under redox-inert conditions, a RuII,II analogue of HKUST-1 was successfully prepared and characterized as a phase-pure microcrystalline powder. X-ray absorption near-edge spectroscopy confirms the oxidation state of the Ru centers of the paddle-wheel nodes in the framework. The porosity of 1371 m2/mmol of RuII,II-HKUST-1 exceeds that of the parent compound HKUST1 (1049 m2/ mmol).

Original languageEnglish
Pages (from-to)12492-12495
Number of pages4
JournalInorganic Chemistry
Volume55
Issue number24
DOIs
StatePublished - 19 Dec 2016

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