Ein Zirconiumamid‐Komplex mit Si‐β‐H–Zr‐Wechselwirkungen

Wolfgang A. Herrmann; Norbert W. Huber; Joachim Behm

doi:10.1002/cber.19921250617

Ein Zirconiumamid‐Komplex mit Si‐β‐H–Zr‐Wechselwirkungen

Wolfgang A. Herrmann, Norbert W. Huber, Joachim Behm

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

A Zirconium Amide Complex with Si‐β‐H–Zr Interactions ZrCl₄ (1) reacts in diethyl ether with Li[N(SiHMe₂)₂] (2) to form the title compound of formula [ZrCl(μ‐Cl){N(SiHMe₂)₂}₂]₂ (3). A single‐crystal X‐ray structure analysis in combination with IR data provides evidence for an unprecedented type of β‐hydrogen interactions between a silicon‐attached hydrogen atom of the bis(dimethylsilyl)amide ligand and the zirconium atom (Zr–N–Si–H).

Original language	German
Pages (from-to)	1405-1407
Number of pages	3
Journal	Chemische Berichte
Volume	125
Issue number	6
DOIs	https://doi.org/10.1002/cber.19921250617
State	Published - Jun 1992

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title = "Ein Zirconiumamid‐Komplex mit Si‐β‐H–Zr‐Wechselwirkungen",

abstract = "A Zirconium Amide Complex with Si‐β‐H–Zr Interactions ZrCl4 (1) reacts in diethyl ether with Li[N(SiHMe2)2] (2) to form the title compound of formula [ZrCl(μ‐Cl)\{N(SiHMe2)2\}2]2 (3). A single‐crystal X‐ray structure analysis in combination with IR data provides evidence for an unprecedented type of β‐hydrogen interactions between a silicon‐attached hydrogen atom of the bis(dimethylsilyl)amide ligand and the zirconium atom (Zr–N–Si–H).",

keywords = "Amido ligands, Zirconium complexes, β‐Hydrogen effect",

author = "Herrmann, \{Wolfgang A.\} and Huber, \{Norbert W.\} and Joachim Behm",

year = "1992",

month = jun,

doi = "10.1002/cber.19921250617",

language = "Deutsch",

volume = "125",

pages = "1405--1407",

journal = "Chemische Berichte",

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T1 - Ein Zirconiumamid‐Komplex mit Si‐β‐H–Zr‐Wechselwirkungen

AU - Herrmann, Wolfgang A.

AU - Huber, Norbert W.

AU - Behm, Joachim

PY - 1992/6

Y1 - 1992/6

N2 - A Zirconium Amide Complex with Si‐β‐H–Zr Interactions ZrCl4 (1) reacts in diethyl ether with Li[N(SiHMe2)2] (2) to form the title compound of formula [ZrCl(μ‐Cl){N(SiHMe2)2}2]2 (3). A single‐crystal X‐ray structure analysis in combination with IR data provides evidence for an unprecedented type of β‐hydrogen interactions between a silicon‐attached hydrogen atom of the bis(dimethylsilyl)amide ligand and the zirconium atom (Zr–N–Si–H).

AB - A Zirconium Amide Complex with Si‐β‐H–Zr Interactions ZrCl4 (1) reacts in diethyl ether with Li[N(SiHMe2)2] (2) to form the title compound of formula [ZrCl(μ‐Cl){N(SiHMe2)2}2]2 (3). A single‐crystal X‐ray structure analysis in combination with IR data provides evidence for an unprecedented type of β‐hydrogen interactions between a silicon‐attached hydrogen atom of the bis(dimethylsilyl)amide ligand and the zirconium atom (Zr–N–Si–H).

KW - Amido ligands

KW - Zirconium complexes

KW - β‐Hydrogen effect

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U2 - 10.1002/cber.19921250617

DO - 10.1002/cber.19921250617

M3 - Artikel

AN - SCOPUS:84944502245

SN - 0009-2940

VL - 125

SP - 1405

EP - 1407

JO - Chemische Berichte

JF - Chemische Berichte

IS - 6

ER -

Ein Zirconiumamid‐Komplex mit Si‐β‐H–Zr‐Wechselwirkungen

Abstract

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