Efficient and convenient palladium-catalyzed amination of allylic alcohols with N-heterocycles

Debasis Banerjee, Rajenahally V. Jagadeesh, Kathrin Junge, Henrik Junge, Matthias Beller

Research output: Contribution to journalArticlepeer-review

51 Scopus citations

Abstract

Atom economic: A commercially available palladium catalyst system is applied for an environmentally benign allylation of electron-deficient N-heterocycles using allylic alcohols (see scheme). The system is also applied for the N-allylation of biologically important uridine and thymidine derivatives.

Original languageEnglish
Pages (from-to)11556-11560
Number of pages5
JournalAngewandte Chemie International Edition in English
Volume51
Issue number46
DOIs
StatePublished - 12 Nov 2012
Externally publishedYes

Keywords

  • allylic substitution
  • amination
  • nitrogen heterocycles
  • palladium
  • sustainable chemistry

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