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Effect of electronic excitation on ultrafast rotational motion of dye molecules

  • Universität Bayreuth

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

Ultrafast polarization spectroscopy with variable probe frequency gives detailed information on rotational motion of dye molecules. We present theoretical and experimental data on phenoxazone 9 dissolved in dioxane and CCl4. For this dye we directly observe different rotational time constants for the S0 and S1 state which are interpreted by electrostatic solute-solvent interaction.

Original languageEnglish
Pages (from-to)297-301
Number of pages5
JournalChemical Physics Letters
Volume92
Issue number3
DOIs
StatePublished - 22 Oct 1982
Externally publishedYes

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