Economic and Straightforward Synthesis of Heteroleptic Silver(I) Complexes bearing NHC and Bidentate Ligands

Ginevra Giobbio; Anaïs Montrieul; Jean François Lohier; Rubén D. Costa; Sylvain Gaillard

doi:10.1002/ejic.202500030

Economic and Straightforward Synthesis of Heteroleptic Silver(I) Complexes bearing NHC and Bidentate Ligands

Ginevra Giobbio, Anaïs Montrieul, Jean François Lohier, Rubén D. Costa, Sylvain Gaillard

Chair of Biogenic Functional Materials

Research output: Contribution to journal › Article › peer-review

Abstract

Herein, we describe an economic, straightforward and selective synthesis for trigonal heteroleptic silver(I) complexes bearing N-Heterocyclic Carbenes (NHC) and bidentate ligands. The procedure allows to synthesize the targeted compounds in mild conditions and short reaction time with various NHC associated with bis-pyridylamine or diphosphine as second ligands. Silver(I) complexes have been fully structurally and photophysically characterized, unveiling the different role and impact of the ligands in the photophysical behavior of this family of silver(I) complexes.

Original language	English
Journal	European Journal of Inorganic Chemistry
DOIs	https://doi.org/10.1002/ejic.202500030
State	Accepted/In press - 2025

Keywords

Heteroleptic complexes
NHC
Photophysical characterization
selectivity
Silver

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10.1002/ejic.202500030

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title = "Economic and Straightforward Synthesis of Heteroleptic Silver(I) Complexes bearing NHC and Bidentate Ligands",

abstract = "Herein, we describe an economic, straightforward and selective synthesis for trigonal heteroleptic silver(I) complexes bearing N-Heterocyclic Carbenes (NHC) and bidentate ligands. The procedure allows to synthesize the targeted compounds in mild conditions and short reaction time with various NHC associated with bis-pyridylamine or diphosphine as second ligands. Silver(I) complexes have been fully structurally and photophysically characterized, unveiling the different role and impact of the ligands in the photophysical behavior of this family of silver(I) complexes.",

keywords = "Heteroleptic complexes, NHC, Photophysical characterization, selectivity, Silver",

author = "Ginevra Giobbio and Ana{\"i}s Montrieul and Lohier, {Jean Fran{\c c}ois} and Costa, {Rub{\'e}n D.} and Sylvain Gaillard",

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doi = "10.1002/ejic.202500030",

language = "English",

journal = "European Journal of Inorganic Chemistry",

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TY - JOUR

T1 - Economic and Straightforward Synthesis of Heteroleptic Silver(I) Complexes bearing NHC and Bidentate Ligands

AU - Giobbio, Ginevra

AU - Montrieul, Anaïs

AU - Lohier, Jean François

AU - Costa, Rubén D.

AU - Gaillard, Sylvain

PY - 2025

Y1 - 2025

N2 - Herein, we describe an economic, straightforward and selective synthesis for trigonal heteroleptic silver(I) complexes bearing N-Heterocyclic Carbenes (NHC) and bidentate ligands. The procedure allows to synthesize the targeted compounds in mild conditions and short reaction time with various NHC associated with bis-pyridylamine or diphosphine as second ligands. Silver(I) complexes have been fully structurally and photophysically characterized, unveiling the different role and impact of the ligands in the photophysical behavior of this family of silver(I) complexes.

AB - Herein, we describe an economic, straightforward and selective synthesis for trigonal heteroleptic silver(I) complexes bearing N-Heterocyclic Carbenes (NHC) and bidentate ligands. The procedure allows to synthesize the targeted compounds in mild conditions and short reaction time with various NHC associated with bis-pyridylamine or diphosphine as second ligands. Silver(I) complexes have been fully structurally and photophysically characterized, unveiling the different role and impact of the ligands in the photophysical behavior of this family of silver(I) complexes.

KW - Heteroleptic complexes

KW - NHC

KW - Photophysical characterization

KW - selectivity

KW - Silver

UR - http://www.scopus.com/inward/record.url?scp=105000942851&partnerID=8YFLogxK

U2 - 10.1002/ejic.202500030

DO - 10.1002/ejic.202500030

M3 - Article

AN - SCOPUS:105000942851

SN - 1434-1948

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

ER -

Economic and Straightforward Synthesis of Heteroleptic Silver(I) Complexes bearing NHC and Bidentate Ligands

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Keywords

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