Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp₂(MeCN)Ti(ν¹-Ge₉{Si(TMS)₃}₃)] and K₃[Cp₂Ti(ν¹-Ge₉{Si(TMS)₃}₂)₂]

Keyphrases

• MeCN 100%
• Cluster Synthesis 100%
• Cluster Characterization 100%
• Ti(III) 100%
• Early Transition Metal Complexes 100%
• Toluene 66%
• Cp2TiCl2 66%
• Elemental Analysis 33%
• Compound II 33%
• Recrystallization 33%
• Molecular Complexes 33%
• Zintl Clusters 33%
• Spectroscopic Analysis 33%
• EPR Spectroscopy 33%
• Rare Example 33%
• Germanide 33%
• Dark Green 33%
• Donor-acceptor Interactions 33%
• Neutral Species 33%
• Low Oxidation State 33%
• Single Crystal X-ray Diffraction (SCXRD) 33%
• Anionic Clusters 33%

Chemistry

• Coordination Compound 100%
• Elemental Analysis 50%
• Donor 50%
• Single Crystal X-Ray Diffraction 50%
• EPR Spectroscopy 50%
• Germanides 50%
• Dark Green 50%
• dimer 50%
• Sweet Orange 50%