Dynamics of ferrocene in molecular sieves probed by Mossbauer spectroscopy and nuclear resonant scattering

T. Asthalter; I. Sergueev; U. Van Bürck; F. E. Wagner; P. Härter; J. Kornatowski; S. Klingelhöfer; P. Behrens

doi:10.1088/1742-6596/217/1/012143

Dynamics of ferrocene in molecular sieves probed by Mossbauer spectroscopy and nuclear resonant scattering

T. Asthalter
, I. Sergueev
, U. Van Bürck
, F. E. Wagner
, P. Härter
, J. Kornatowski
, S. Klingelhöfer
, P. Behrens

Natural Sciences

Research output: Contribution to journal › Conference article › peer-review

Abstract

A detailed study on the slow dynamics of ferrocene in the unidimensional channels of the molecular sieves SSZ-24 and AlPO₄-5 has been carried out, using Mössbauer spectroscopy (MS), nuclear forward scattering (NFS) and synchrotron radiation-based perturbed angular correlations (SRPAC). In both host systems, anisotropic rotational dynamics is observed above 100 K. For SSZ-24, this anisotropy persists even above the bulk melting temperature of ferrocene. Various theoretical models are exploited for the study of anisotropic discrete jump rotations for the first time. The experimental data can be described fairly well by a jump model that involves reorientations of the molecular axis on a cone mantle with an opening angle dependant on temperature.

Original language	English
Article number	012143
Journal	Journal of Physics: Conference Series
Volume	217
Issue number	1
DOIs	https://doi.org/10.1088/1742-6596/217/1/012143
State	Published - 2010
Event	International Conference on the Applications of the Mossbauer Effect, ICAME 2009 - Vienna, Austria Duration: 19 Jul 2009 → 24 Jul 2009

Access to Document

10.1088/1742-6596/217/1/012143

Cite this

@article{1439dad96f6241a1a2c8f0c152edca7b,

title = "Dynamics of ferrocene in molecular sieves probed by Mossbauer spectroscopy and nuclear resonant scattering",

abstract = "A detailed study on the slow dynamics of ferrocene in the unidimensional channels of the molecular sieves SSZ-24 and AlPO4-5 has been carried out, using M{\"o}ssbauer spectroscopy (MS), nuclear forward scattering (NFS) and synchrotron radiation-based perturbed angular correlations (SRPAC). In both host systems, anisotropic rotational dynamics is observed above 100 K. For SSZ-24, this anisotropy persists even above the bulk melting temperature of ferrocene. Various theoretical models are exploited for the study of anisotropic discrete jump rotations for the first time. The experimental data can be described fairly well by a jump model that involves reorientations of the molecular axis on a cone mantle with an opening angle dependant on temperature.",

author = "T. Asthalter and I. Sergueev and \{Van B{\"u}rck\}, U. and Wagner, \{F. E.\} and P. H{\"a}rter and J. Kornatowski and S. Klingelh{\"o}fer and P. Behrens",

year = "2010",

doi = "10.1088/1742-6596/217/1/012143",

language = "English",

volume = "217",

journal = "Journal of Physics: Conference Series",

issn = "1742-6588",

publisher = "IOP Publishing Ltd.",

number = "1",

note = "International Conference on the Applications of the Mossbauer Effect, ICAME 2009 ; Conference date: 19-07-2009 Through 24-07-2009",

}

TY - JOUR

T1 - Dynamics of ferrocene in molecular sieves probed by Mossbauer spectroscopy and nuclear resonant scattering

AU - Asthalter, T.

AU - Sergueev, I.

AU - Van Bürck, U.

AU - Wagner, F. E.

AU - Härter, P.

AU - Kornatowski, J.

AU - Klingelhöfer, S.

AU - Behrens, P.

PY - 2010

Y1 - 2010

N2 - A detailed study on the slow dynamics of ferrocene in the unidimensional channels of the molecular sieves SSZ-24 and AlPO4-5 has been carried out, using Mössbauer spectroscopy (MS), nuclear forward scattering (NFS) and synchrotron radiation-based perturbed angular correlations (SRPAC). In both host systems, anisotropic rotational dynamics is observed above 100 K. For SSZ-24, this anisotropy persists even above the bulk melting temperature of ferrocene. Various theoretical models are exploited for the study of anisotropic discrete jump rotations for the first time. The experimental data can be described fairly well by a jump model that involves reorientations of the molecular axis on a cone mantle with an opening angle dependant on temperature.

AB - A detailed study on the slow dynamics of ferrocene in the unidimensional channels of the molecular sieves SSZ-24 and AlPO4-5 has been carried out, using Mössbauer spectroscopy (MS), nuclear forward scattering (NFS) and synchrotron radiation-based perturbed angular correlations (SRPAC). In both host systems, anisotropic rotational dynamics is observed above 100 K. For SSZ-24, this anisotropy persists even above the bulk melting temperature of ferrocene. Various theoretical models are exploited for the study of anisotropic discrete jump rotations for the first time. The experimental data can be described fairly well by a jump model that involves reorientations of the molecular axis on a cone mantle with an opening angle dependant on temperature.

UR - https://www.scopus.com/pages/publications/77954669793

U2 - 10.1088/1742-6596/217/1/012143

DO - 10.1088/1742-6596/217/1/012143

M3 - Conference article

AN - SCOPUS:77954669793

SN - 1742-6588

VL - 217

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

IS - 1

M1 - 012143

T2 - International Conference on the Applications of the Mossbauer Effect, ICAME 2009

Y2 - 19 July 2009 through 24 July 2009

ER -

Dynamics of ferrocene in molecular sieves probed by Mossbauer spectroscopy and nuclear resonant scattering

Abstract

Access to Document

Other files and links

Fingerprint

Cite this