Domino catalysis: Palladium-catalyzed carbonylation of allylic alcohols to β,γ-unsaturated esters

Qiang Liu, Lipeng Wu, Haijun Jiao, Xianjie Fang, Ralf Jackstell, Matthias Beller

Research output: Contribution to journalArticlepeer-review

68 Scopus citations

Abstract

Make it green: The Pd-catalyzed carbonylation of allylic alcohols with aliphatic alcohols represents a cost-effective, salt-free, and atom-economic carbonylation process generating water as the sole by-product. Mechanistic studies uncovered a new domino C-O coupling/carbonylation reaction pathway.

Original languageEnglish
Pages (from-to)8064-8068
Number of pages5
JournalAngewandte Chemie International Edition in English
Volume52
Issue number31
DOIs
StatePublished - 29 Jul 2013
Externally publishedYes

Keywords

  • C-O coupling
  • allylic alcohols
  • carbonylation
  • domino reactions
  • palladium

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