Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

Saurav Bhattacharya; Wassim W. Ayass; Dereje H. Taffa; Andreas Schneemann; A. Lisa Semrau; Suttipong Wannapaiboon; Philipp J. Altmann; Alexander Pöthig; Talha Nisar; Torsten Balster; Nicholas C. Burtch; Veit Wagner; Roland A. Fischer; Michael Wark; Ulrich Kortz

doi:10.1021/jacs.8b13397

Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

Saurav Bhattacharya
, Wassim W. Ayass
, Dereje H. Taffa
, Andreas Schneemann
, A. Lisa Semrau
, Suttipong Wannapaiboon
, Philipp J. Altmann
, Alexander Pöthig
, Talha Nisar
, Torsten Balster
, Nicholas C. Burtch
, Veit Wagner
, Roland A. Fischer
, Michael Wark
, Ulrich Kortz

Jacobs University Bremen
Universität Oldenburg
Technical University of Munich
Sandia National Laboratories, California

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd₁₃O₈(AsO₄)₈H₆]^8- decorated by four Ba²⁺ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

Original language	English
Pages (from-to)	3385-3389
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	141
Issue number	8
DOIs	https://doi.org/10.1021/jacs.8b13397
State	Published - 27 Feb 2019

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Bhattacharya, S., Ayass, W. W., Taffa, D. H., Schneemann, A., Semrau, A. L., Wannapaiboon, S., Altmann, P. J., Pöthig, A., Nisar, T., Balster, T., Burtch, N. C., Wagner, V., Fischer, R. A., Wark, M., & Kortz, U. (2019). Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks. Journal of the American Chemical Society, 141(8), 3385-3389. https://doi.org/10.1021/jacs.8b13397

@article{6f95897138d1495388203fa762116804,

title = "Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks",

abstract = "Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.",

author = "Saurav Bhattacharya and Ayass, \{Wassim W.\} and Taffa, \{Dereje H.\} and Andreas Schneemann and Semrau, \{A. Lisa\} and Suttipong Wannapaiboon and Altmann, \{Philipp J.\} and Alexander P{\"o}thig and Talha Nisar and Torsten Balster and Burtch, \{Nicholas C.\} and Veit Wagner and Fischer, \{Roland A.\} and Michael Wark and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = feb,

day = "27",

doi = "10.1021/jacs.8b13397",

language = "English",

volume = "141",

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Bhattacharya, S, Ayass, WW, Taffa, DH, Schneemann, A, Semrau, AL, Wannapaiboon, S, Altmann, PJ, Pöthig, A, Nisar, T, Balster, T, Burtch, NC, Wagner, V, Fischer, RA, Wark, M & Kortz, U 2019, 'Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks', Journal of the American Chemical Society, vol. 141, no. 8, pp. 3385-3389. https://doi.org/10.1021/jacs.8b13397

TY - JOUR

T1 - Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

AU - Bhattacharya, Saurav

AU - Ayass, Wassim W.

AU - Taffa, Dereje H.

AU - Schneemann, Andreas

AU - Semrau, A. Lisa

AU - Wannapaiboon, Suttipong

AU - Altmann, Philipp J.

AU - Pöthig, Alexander

AU - Nisar, Talha

AU - Balster, Torsten

AU - Burtch, Nicholas C.

AU - Wagner, Veit

AU - Fischer, Roland A.

AU - Wark, Michael

AU - Kortz, Ulrich

PY - 2019/2/27

Y1 - 2019/2/27

N2 - Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

AB - Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

UR - https://www.scopus.com/pages/publications/85062258045

U2 - 10.1021/jacs.8b13397

DO - 10.1021/jacs.8b13397

M3 - Article

C2 - 30712351

AN - SCOPUS:85062258045

SN - 0002-7863

VL - 141

SP - 3385

EP - 3389

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 8

ER -

Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

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