Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

Saurav Bhattacharya; Wassim W. Ayass; Dereje H. Taffa; Andreas Schneemann; A. Lisa Semrau; Suttipong Wannapaiboon; Philipp J. Altmann; Alexander Pöthig; Talha Nisar; Torsten Balster; Nicholas C. Burtch; Veit Wagner; Roland A. Fischer; Michael Wark; Ulrich Kortz

doi:10.1021/jacs.8b13397

Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

Saurav Bhattacharya, Wassim W. Ayass, Dereje H. Taffa, Andreas Schneemann, A. Lisa Semrau, Suttipong Wannapaiboon, Philipp J. Altmann, Alexander Pöthig, Talha Nisar, Torsten Balster, Nicholas C. Burtch, Veit Wagner, Roland A. Fischer, Michael Wark, Ulrich Kortz

Chair of Inorganic and Organometallic Chemistry

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd₁₃O₈(AsO₄)₈H₆]^8- decorated by four Ba²⁺ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

Original language	English
Pages (from-to)	3385-3389
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	141
Issue number	8
DOIs	https://doi.org/10.1021/jacs.8b13397
State	Published - 27 Feb 2019

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Bhattacharya, S., Ayass, W. W., Taffa, D. H., Schneemann, A., Semrau, A. L., Wannapaiboon, S., Altmann, P. J., Pöthig, A., Nisar, T., Balster, T., Burtch, N. C., Wagner, V., Fischer, R. A., Wark, M., & Kortz, U. (2019). Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks. Journal of the American Chemical Society, 141(8), 3385-3389. https://doi.org/10.1021/jacs.8b13397

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title = "Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks",

abstract = "Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.",

author = "Saurav Bhattacharya and Ayass, {Wassim W.} and Taffa, {Dereje H.} and Andreas Schneemann and Semrau, {A. Lisa} and Suttipong Wannapaiboon and Altmann, {Philipp J.} and Alexander P{\"o}thig and Talha Nisar and Torsten Balster and Burtch, {Nicholas C.} and Veit Wagner and Fischer, {Roland A.} and Michael Wark and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

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day = "27",

doi = "10.1021/jacs.8b13397",

language = "English",

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Bhattacharya, S, Ayass, WW, Taffa, DH, Schneemann, A, Semrau, AL, Wannapaiboon, S, Altmann, PJ, Pöthig, A, Nisar, T, Balster, T, Burtch, NC, Wagner, V, Fischer, RA, Wark, M & Kortz, U 2019, 'Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks', Journal of the American Chemical Society, vol. 141, no. 8, pp. 3385-3389. https://doi.org/10.1021/jacs.8b13397

TY - JOUR

T1 - Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

AU - Bhattacharya, Saurav

AU - Ayass, Wassim W.

AU - Taffa, Dereje H.

AU - Schneemann, Andreas

AU - Semrau, A. Lisa

AU - Wannapaiboon, Suttipong

AU - Altmann, Philipp J.

AU - Pöthig, Alexander

AU - Nisar, Talha

AU - Balster, Torsten

AU - Burtch, Nicholas C.

AU - Wagner, Veit

AU - Fischer, Roland A.

AU - Wark, Michael

AU - Kortz, Ulrich

PY - 2019/2/27

Y1 - 2019/2/27

N2 - Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

AB - Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13O8(AsO4)8H6]8- decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.

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U2 - 10.1021/jacs.8b13397

DO - 10.1021/jacs.8b13397

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AN - SCOPUS:85062258045

SN - 0002-7863

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EP - 3389

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 8

ER -

Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks

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