Diruthenium σ-alkynyl complexes as potential building blocks for heterometallic molecular rods

Jing Lin Zuo; Eberhardt Herdtweck; Fritz E. Kühn

doi:10.1039/b111068n

Diruthenium σ-alkynyl complexes as potential building blocks for heterometallic molecular rods

Jing Lin Zuo, Eberhardt Herdtweck, Fritz E. Kühn

Associate Professorship of Molecular Catalysis

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Diruthenium(III) bis(σ-pyridylacetylide) complexes can be utilized for axially connecting to monometallic organometallic units in order to construct heterobimetallic building blocks for molecular rods; the synthesis and characterization of an exemplary rhenium-diruthenium-rhenium complex is described, which is stable to air, moisture and a broad variety of organic solvents and which displays electron delocalisation along the propagation axis.

Original language	English
Pages (from-to)	1244-1246
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/b111068n
State	Published - 2002

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abstract = "Diruthenium(III) bis(σ-pyridylacetylide) complexes can be utilized for axially connecting to monometallic organometallic units in order to construct heterobimetallic building blocks for molecular rods; the synthesis and characterization of an exemplary rhenium-diruthenium-rhenium complex is described, which is stable to air, moisture and a broad variety of organic solvents and which displays electron delocalisation along the propagation axis.",

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AB - Diruthenium(III) bis(σ-pyridylacetylide) complexes can be utilized for axially connecting to monometallic organometallic units in order to construct heterobimetallic building blocks for molecular rods; the synthesis and characterization of an exemplary rhenium-diruthenium-rhenium complex is described, which is stable to air, moisture and a broad variety of organic solvents and which displays electron delocalisation along the propagation axis.

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JO - Journal of the Chemical Society. Dalton Transactions

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Diruthenium σ-alkynyl complexes as potential building blocks for heterometallic molecular rods

Abstract

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