Direct Synthesis and Bonding Properties of the First μ2-η2,η2-Allyl-Bridged Diiridium Complex

Korbinian Riener; Teresa K. Zimmermann; Alexander Pöthig; Wolfgang A. Herrmann; Fritz E. Kühn

doi:10.1021/acs.inorgchem.5b00671

Direct Synthesis and Bonding Properties of the First μ²-η²,η²-Allyl-Bridged Diiridium Complex

Korbinian Riener, Teresa K. Zimmermann, Alexander Pöthig, Wolfgang A. Herrmann, Fritz E. Kühn

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The direct synthesis of the first μ²-η²,η²-allyl-bridged diiridium complex ([2]⁺), bearing the uncommon counterion [IrCl₂(COD)]^- ([3]^-), is described. Both bridging moieties in [2]⁺, namely, allyl and acetate, are introduced in a single reaction step from [{IrCl(COD)}₂] (1) and allyl acetate. A combination of X-ray crystallography and density functional theory calculations reveals pronounced metal-allyl π-back-bonding.

Original language	English
Pages (from-to)	4600-4602
Number of pages	3
Journal	Inorganic Chemistry
Volume	54
Issue number	10
DOIs	https://doi.org/10.1021/acs.inorgchem.5b00671
State	Published - 18 May 2015

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title = "Direct Synthesis and Bonding Properties of the First μ2-η2,η2-Allyl-Bridged Diiridium Complex",

abstract = "The direct synthesis of the first μ2-η2,η2-allyl-bridged diiridium complex ([2]+), bearing the uncommon counterion [IrCl2(COD)]- ([3]-), is described. Both bridging moieties in [2]+, namely, allyl and acetate, are introduced in a single reaction step from [{IrCl(COD)}2] (1) and allyl acetate. A combination of X-ray crystallography and density functional theory calculations reveals pronounced metal-allyl π-back-bonding.",

author = "Korbinian Riener and Zimmermann, {Teresa K.} and Alexander P{\"o}thig and Herrmann, {Wolfgang A.} and K{\"u}hn, {Fritz E.}",

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T1 - Direct Synthesis and Bonding Properties of the First μ2-η2,η2-Allyl-Bridged Diiridium Complex

AU - Riener, Korbinian

AU - Zimmermann, Teresa K.

AU - Pöthig, Alexander

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz E.

PY - 2015/5/18

Y1 - 2015/5/18

N2 - The direct synthesis of the first μ2-η2,η2-allyl-bridged diiridium complex ([2]+), bearing the uncommon counterion [IrCl2(COD)]- ([3]-), is described. Both bridging moieties in [2]+, namely, allyl and acetate, are introduced in a single reaction step from [{IrCl(COD)}2] (1) and allyl acetate. A combination of X-ray crystallography and density functional theory calculations reveals pronounced metal-allyl π-back-bonding.

AB - The direct synthesis of the first μ2-η2,η2-allyl-bridged diiridium complex ([2]+), bearing the uncommon counterion [IrCl2(COD)]- ([3]-), is described. Both bridging moieties in [2]+, namely, allyl and acetate, are introduced in a single reaction step from [{IrCl(COD)}2] (1) and allyl acetate. A combination of X-ray crystallography and density functional theory calculations reveals pronounced metal-allyl π-back-bonding.

UR - http://www.scopus.com/inward/record.url?scp=84929591239&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.5b00671

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M3 - Article

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VL - 54

SP - 4600

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 10

ER -

Direct Synthesis and Bonding Properties of the First μ²-η²,η²-Allyl-Bridged Diiridium Complex

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