Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

S. Kissling; M. W. Lehenmeier; P. T. Altenbuchner; A. Kronast; M. Reiter; P. Deglmann; U. B. Seemann; B. Rieger

doi:10.1039/c5cc00784d

Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO₂

S. Kissling, M. W. Lehenmeier, P. T. Altenbuchner, A. Kronast, M. Reiter, P. Deglmann, U. B. Seemann, B. Rieger

Wacker-Chair of Macromolecular Chemistry

Research output: Contribution to journal › Article › peer-review

138 Scopus citations

Abstract

A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155 000 h^-1. These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO₂.

Original language	English
Pages (from-to)	4579-4582
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	22
DOIs	https://doi.org/10.1039/c5cc00784d
State	Published - 18 Mar 2015

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title = "Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2",

abstract = "A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155 000 h-1. These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.",

author = "S. Kissling and Lehenmeier, {M. W.} and Altenbuchner, {P. T.} and A. Kronast and M. Reiter and P. Deglmann and Seemann, {U. B.} and B. Rieger",

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T1 - Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2

AU - Kissling, S.

AU - Lehenmeier, M. W.

AU - Altenbuchner, P. T.

AU - Kronast, A.

AU - Reiter, M.

AU - Deglmann, P.

AU - Seemann, U. B.

AU - Rieger, B.

PY - 2015/3/18

Y1 - 2015/3/18

N2 - A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155 000 h-1. These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.

AB - A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155 000 h-1. These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.

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DO - 10.1039/c5cc00784d

M3 - Article

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VL - 51

SP - 4579

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JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO₂

Abstract

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